一维带状SnO<sub>2</sub>的电子传输性能

引用本文: 李晓宁, 白守礼, 杨文胜, 陈霭璠, 孙丽娜, 林原, 张敬波. 一维带状SnO₂的电子传输性能[J]. 物理化学学报, 2012, 28(07): 1797-1802. doi: 10.3866/PKU.WHXB201205081 shu

Citation: LI Xiao-Ning, BAI Shou-Li, YANG Wen-Sheng, CHEN Ai-Fan, SUN Li-Na, LIN Yuan, ZHANG Jing-Bo. Electron Transport Properties of One-Dimensional Structural SnO₂ Belts[J]. Acta Physico-Chimica Sinica, 2012, 28(07): 1797-1802. doi: 10.3866/PKU.WHXB201205081 shu

一维带状SnO₂的电子传输性能

基金项目:
国家自然科学基金(20873162, 51102011) (20873162, 51102011)

北京自然科学基金(8102028, 8112022)资助项目 (8102028, 8112022)

摘要:

采用水辅助化学气相沉积法制备了结晶性好的一维带状SnO₂. 分别以小粒径锡粉和金修饰的小粒径锡粉作为反应原料制得带宽度不同的带状SnO₂, 小粒径锡粉作为反应原料能提高带状SnO₂的产率. 将所得SnO₂带和SnO₂纳米颗粒按不同比例混合配制成胶体, 采用刮涂法制备含不同比例纳米颗粒和纳米带的复合SnO₂薄膜并组装染料敏化太阳能电池(DSSCs)来评价带状SnO₂的电子输运性能. 组装的太阳能电池表现出与复合纳晶薄膜中一维SnO₂带的带宽度和所含比例密切相关的光电性能. 通过强度调制光电流谱的测量确定复合SnO₂薄膜的电子传输速率, 并进一步分析一维材料所具有的良好电子传输性能对光电流增加的贡献. 因为一维SnO₂带在复合纳晶薄膜中作为电子输运的快速通道可以加快电子的输运速度, 所以以适宜的比例添加具有合适宽度的一维SnO₂带可以明显提高太阳能电池的光电性能.

关键词:

English

Electron Transport Properties of One-Dimensional Structural SnO₂ Belts

1.
1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China;
2. Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
3. Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300387, P. R. China
Received Date: 02 March 2012
Available Online: 07 June 2012
Fund Project:
国家自然科学基金(20873162, 51102011)

北京自然科学基金(8102028, 8112022)资助项目

Abstract:

Well-crystallized one-dimensional (1D) structural SnO₂ belts are synthesized using a simple water-assisted chemical vapor deposition method. To increase the yield of SnO₂ belts, small Sn particles with and without Au-modifications are used as source materials to grow different width SnO₂ belts. Dye-sensitized solar cells (DSSCs) fabricated using the composite (nanoparticle/nanobelt) SnO₂ thin films, are used to evaluate the electron transport properties of the SnO₂ belts. Pastes containing different ratios of nanoparticles and belts are used to prepare the composite film by the doctor-blade method. The DSSCs exhibit different photovoltaic performances which are dependent on the nanoparticle/nanobelt ratio and width of the SnO₂ belts in the thin film. The enhanced electron transport properties of the composite films containing the SnO₂ belts is evaluated using intensity modulated photocurrent spectroscopy (IMPS). 1D SnO₂ belts with a particular belt width improve the photovoltaic performance by providing electron paths to accelerate electron transport in the composite nanocrystalline thin films.

Key words:

1. [1]
  
  (1) O'Regan, B.; Grätzel, M. Nature 1991, 353, 737. doi: 10.1038/353737a0
  (1) O'Regan, B.; Grätzel, M. Nature 1991, 353, 737. doi: 10.1038/353737a0
2. [2]
  (2) Grätzel, M. J. Photochem. Photobiol. 2004, 164, 3. doi: 10.1016/j.jphotochem.2004.02.023(2) Grätzel, M. J. Photochem. Photobiol. 2004, 164, 3. doi: 10.1016/j.jphotochem.2004.02.023
3. [3]
  (3) Nazeeruddin, M. K.; Péchy, P.; Renouard, T.; Zakeeruddin, S.M., Humphry-Baker, R.; Comte, P.; Liska, P.; Cevey, L.; Costa,E.; Shklover, V.; Spiccia, L.; Deacon, G. B.; Bignozzi, C. A.;Grätzel, M. J. Am. Chem. Soc. 2001, 123, 1613. doi: 10.1021/ja003299u(3) Nazeeruddin, M. K.; Péchy, P.; Renouard, T.; Zakeeruddin, S.M., Humphry-Baker, R.; Comte, P.; Liska, P.; Cevey, L.; Costa,E.; Shklover, V.; Spiccia, L.; Deacon, G. B.; Bignozzi, C. A.;Grätzel, M. J. Am. Chem. Soc. 2001, 123, 1613. doi: 10.1021/ja003299u
4. [4]
  (4) Pagliaro, M.; Palmisano, G.; Ciriminna, R.; Loddo, V. Energy Environ. Sci. 2009, 2, 838. doi: 10.1039/b903030a(4) Pagliaro, M.; Palmisano, G.; Ciriminna, R.; Loddo, V. Energy Environ. Sci. 2009, 2, 838. doi: 10.1039/b903030a
5. [5]
  (5) Berger, T.; Lana-Villarreal, T.; Monllor-Satoca, D.; Gómez, R.J. Phys. Chem. C 2007, 111, 9936. doi: 10.1021/jp071438p(5) Berger, T.; Lana-Villarreal, T.; Monllor-Satoca, D.; Gómez, R.J. Phys. Chem. C 2007, 111, 9936. doi: 10.1021/jp071438p
6. [6]
  (6) Chen, D. H.; Huang, F. Z.; Cheng, Y. B.; Caruso, R. A. Adv. Mater. 2009, 21, 2206. doi: 10.1002/adma.200802603(6) Chen, D. H.; Huang, F. Z.; Cheng, Y. B.; Caruso, R. A. Adv. Mater. 2009, 21, 2206. doi: 10.1002/adma.200802603
7. [7]
  (7) Qian, J. F.; Liu, P.; Xiao, Y.; Jiang, Y.; Cao, Y. L.; Ai, X. P.;Yang, H. X. Adv. Mater. 2009, 21, 3633.(7) Qian, J. F.; Liu, P.; Xiao, Y.; Jiang, Y.; Cao, Y. L.; Ai, X. P.;Yang, H. X. Adv. Mater. 2009, 21, 3633.
8. [8]
  (8) Bierman, M. J.; Jin, S. Energy Environ. Sci. 2009, 2, 1050. doi: 10.1039/b912095e(8) Bierman, M. J.; Jin, S. Energy Environ. Sci. 2009, 2, 1050. doi: 10.1039/b912095e
9. [9]
  (9) Xiao, Y. M.;Wu, J. H.; Yue, G. T.; Lin, J. M.; Huang, M. L.; Fan,L. Q.; Lan, Z. Acta Phys. -Chim. Sin. 2012, 28, 578. [肖尧明,吴季怀, 岳根田, 林建明, 黄妙良, 范乐庆, 兰章. 物理化学学报, 2012, 28, 578.] doi: 10.3866/PKU.WHXB201201032(9) Xiao, Y. M.;Wu, J. H.; Yue, G. T.; Lin, J. M.; Huang, M. L.; Fan,L. Q.; Lan, Z. Acta Phys. -Chim. Sin. 2012, 28, 578. [肖尧明,吴季怀, 岳根田, 林建明, 黄妙良, 范乐庆, 兰章. 物理化学学报, 2012, 28, 578.] doi: 10.3866/PKU.WHXB201201032
10. [10]
  (10) Wang, Z. L. Adv. Mater. 2000, 12, 1295. doi: 10.1002/1521-4095(200009)12:17<1295::AID-ADMA1295>3.0.CO;2-B(10) Wang, Z. L. Adv. Mater. 2000, 12, 1295. doi: 10.1002/1521-4095(200009)12:17<1295::AID-ADMA1295>3.0.CO;2-B
11. [11]
  (11) Hu, J. T.; Odom, T.W.; Lieber, C. M. Accounts Chem. Res. 1999,32, 435. doi: 10.1021/ar9700365(11) Hu, J. T.; Odom, T.W.; Lieber, C. M. Accounts Chem. Res. 1999,32, 435. doi: 10.1021/ar9700365
12. [12]
  (12) Xia, Y. N.; Yang, P. D.; Sun, Y. G.;Wu, Y. Y.; Mayers, B.; Gates,B.; Yin, Y. D.; Kim, F.; Yan, Y. Q. Adv. Mater. 2003, 15, 353.doi: 10.1002/adma.200390087(12) Xia, Y. N.; Yang, P. D.; Sun, Y. G.;Wu, Y. Y.; Mayers, B.; Gates,B.; Yin, Y. D.; Kim, F.; Yan, Y. Q. Adv. Mater. 2003, 15, 353.doi: 10.1002/adma.200390087
13. [13]
  (13) Kang, S. H.; Choi, S. H.; Kang, M. S.; Kim, J. Y.; Kim, H. S.;Hyeon, T.; Sung, Y. E. Adv. Mater. 2008, 20, 54. doi: 10.1002/adma.200701819(13) Kang, S. H.; Choi, S. H.; Kang, M. S.; Kim, J. Y.; Kim, H. S.;Hyeon, T.; Sung, Y. E. Adv. Mater. 2008, 20, 54. doi: 10.1002/adma.200701819
14. [14]
  (14) Mor, G. K.; Shankar, K.; Paulose, M.; Varghese, O. K.; Grimes,C. A. Nano Lett. 2006, 6, 215. doi: 10.1021/nl052099j(14) Mor, G. K.; Shankar, K.; Paulose, M.; Varghese, O. K.; Grimes,C. A. Nano Lett. 2006, 6, 215. doi: 10.1021/nl052099j
15. [15]
  (15) Feng, X. J.; Shankar, K.; Varghese, O. K.; Paulose, M.;Latempa, T. J.; Grimes, C. A. Nano Lett. 2008, 8, 3781. doi: 10.1021/nl802096a(15) Feng, X. J.; Shankar, K.; Varghese, O. K.; Paulose, M.;Latempa, T. J.; Grimes, C. A. Nano Lett. 2008, 8, 3781. doi: 10.1021/nl802096a
16. [16]
  (16) Zhu, K.; Neale, N. R.; Miedaner, A.; Frank, A. J. Nano Lett.2007, 7, 69. doi: 10.1021/nl062000o(16) Zhu, K.; Neale, N. R.; Miedaner, A.; Frank, A. J. Nano Lett.2007, 7, 69. doi: 10.1021/nl062000o
17. [17]
  (17) Suzuki, Y.; Ngamsinlapasathian, S.; Yoshida, R.; Yoshikawa, S.Central Eur. J. Chem. 2006, 4, 476. doi: 10.2478/s11532-006-0015-3(17) Suzuki, Y.; Ngamsinlapasathian, S.; Yoshida, R.; Yoshikawa, S.Central Eur. J. Chem. 2006, 4, 476. doi: 10.2478/s11532-006-0015-3
18. [18]
  (18) Asa e, K.; Suzuki, Y.; Ngamsinlapasathian, S.; Yoshikawa, S.J. Phys.: Conf. Ser. 2007, 61, 1112. doi: 10.1088/1742-6596/61/1/220(18) Asa e, K.; Suzuki, Y.; Ngamsinlapasathian, S.; Yoshikawa, S.J. Phys.: Conf. Ser. 2007, 61, 1112. doi: 10.1088/1742-6596/61/1/220
19. [19]
  (19) Prins, M.W. J.; Grosse-Holz, K. O.; Cillessen, J. F. M.; Feiner,L. F. J. Appl. Phys. 1998, 83, 888. doi: 10.1063/1.366773(19) Prins, M.W. J.; Grosse-Holz, K. O.; Cillessen, J. F. M.; Feiner,L. F. J. Appl. Phys. 1998, 83, 888. doi: 10.1063/1.366773
20. [20]
  (20) Dinh, N. N.; Bernard, M. C.; ff, A. H. L.; Stergiopoulos, T.;Falaras, P. Comptes Rendus Chimie 2006, 9, 676. doi: 10.1016/j.crci.2005.02.042(20) Dinh, N. N.; Bernard, M. C.; ff, A. H. L.; Stergiopoulos, T.;Falaras, P. Comptes Rendus Chimie 2006, 9, 676. doi: 10.1016/j.crci.2005.02.042
21. [21]
  (21) Xia, J. B.; Li, F. Y.; Yang, S. M.; Huang, C. H. Chin. Chem. Lett.2004, 5, 619.(21) Xia, J. B.; Li, F. Y.; Yang, S. M.; Huang, C. H. Chin. Chem. Lett.2004, 5, 619.
22. [22]
  (22) Yin,W. Y.;Wei, B. Q.; Hu, C.W. Chem. Phys. Lett. 2009, 471,11. doi: 10.1016/j.cplett.2009.02.021(22) Yin,W. Y.;Wei, B. Q.; Hu, C.W. Chem. Phys. Lett. 2009, 471,11. doi: 10.1016/j.cplett.2009.02.021
23. [23]
  (23) Liu, R. H.; Zhang, S.; Xia, X. Y.; Yun, D. Q.; Bian, Z. Q.; Zhao,Y. L. Acta Phys. -Chim. Sin. 2011, 27, 1701. [刘润花, 张森,夏新元, 云大钦, 卞祖强, 赵永亮. 物理化学学报, 2011, 27,1701.] doi: 10.3866/PKU.WHXB20110734(23) Liu, R. H.; Zhang, S.; Xia, X. Y.; Yun, D. Q.; Bian, Z. Q.; Zhao,Y. L. Acta Phys. -Chim. Sin. 2011, 27, 1701. [刘润花, 张森,夏新元, 云大钦, 卞祖强, 赵永亮. 物理化学学报, 2011, 27,1701.] doi: 10.3866/PKU.WHXB20110734
24. [24]
  (24) Dloczik, L.; Ileperuma, O.; Lauermann, I.; Peter, L. M.;Ponomarev, E. A.; Redmond, G.; Shaw, N. J.; Uhlendorf, I.J. Phys. Chem. B 1997, 101, 10281. doi: 10.1021/jp972466i(24) Dloczik, L.; Ileperuma, O.; Lauermann, I.; Peter, L. M.;Ponomarev, E. A.; Redmond, G.; Shaw, N. J.; Uhlendorf, I.J. Phys. Chem. B 1997, 101, 10281. doi: 10.1021/jp972466i
25. [25]
  (25) Qu, J.; Gao, X. P.; Li, G. R.; Jiang, Q.W.; Yan, T. Y. J. Phys. Chem. C 2009, 113, 3359. doi: 10.1021/jp810692t(25) Qu, J.; Gao, X. P.; Li, G. R.; Jiang, Q.W.; Yan, T. Y. J. Phys. Chem. C 2009, 113, 3359. doi: 10.1021/jp810692t
26. [26]
  (26) Pan, K.; Dong, Y. Z.; Tian, C. G.; Zhou,W.; Tian, G. H.; Zhao,B. F.; Fu, H. G. Electrochim. Acta 2009, 54, 7350. doi: 10.1016/j.electacta.2009.07.065(26) Pan, K.; Dong, Y. Z.; Tian, C. G.; Zhou,W.; Tian, G. H.; Zhao,B. F.; Fu, H. G. Electrochim. Acta 2009, 54, 7350. doi: 10.1016/j.electacta.2009.07.065
27. [27]
  (27) nzalez-Valls, I.; Lira-Cantu, M. Energy Environ. Sci. 2009, 2,19. doi: 10.1039/b811536b(27) nzalez-Valls, I.; Lira-Cantu, M. Energy Environ. Sci. 2009, 2,19. doi: 10.1039/b811536b
28. [28]
  (28) Yang, Z. Z.; Xu, T.; Ito, Y. S.;Welp, U.; Kwoko,W. K. J. Phys. Chem. C 2009, 113, 20521. doi: 10.1021/jp908678x
  (28) Yang, Z. Z.; Xu, T.; Ito, Y. S.;Welp, U.; Kwoko,W. K. J. Phys. Chem. C 2009, 113, 20521. doi: 10.1021/jp908678x

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

一维带状SnO₂的电子传输性能

English

Electron Transport Properties of One-Dimensional Structural SnO₂ Belts

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

一维带状SnO2的电子传输性能

English

Electron Transport Properties of One-Dimensional Structural SnO2 Belts

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CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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Electron Transport Properties of One-Dimensional Structural SnO₂ Belts

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