醇-可聚合表面活性剂混合胶束法合成微嵌段缔合聚合物及其流变性

引用本文: 柳建新, 郭拥军, 祝仰文, 杨红萍, 杨雪杉, 钟金杭, 李华兵, 罗平亚. 醇-可聚合表面活性剂混合胶束法合成微嵌段缔合聚合物及其流变性[J]. 物理化学学报, 2012, 28(07): 1757-1763. doi: 10.3866/PKU.WHXB201204231 shu

Citation: LIU Jian-Xin, GUO Yong-Jun, ZHU Yang-Wen, YANG Hong-Ping, YANG Xue-Shan, ZHONG Jin-Hang, LI Hua-Bing, LUO Ping-Ya. Polymerization of Micro-Block Associative Polymer with Alcohol-Surfmer Mixed Micellar Method and Their Rheological Properties[J]. Acta Physico-Chimica Sinica, 2012, 28(07): 1757-1763. doi: 10.3866/PKU.WHXB201204231 shu

醇-可聚合表面活性剂混合胶束法合成微嵌段缔合聚合物及其流变性

基金项目:
国家科技重大专项(2011ZX05011)资助项目 (2011ZX05011)

摘要:

低碳醇与可聚合表面活性剂(surfmer)可以形成混合胶束, 本文通过稳态荧光猝灭法(SSFQ)测定了该混合胶束中可聚合表面活性剂的聚集数, 并通过绝热聚合和后水解工艺合成出不同微嵌段长度的较高分子量(M_w)缔合聚合物聚(丙烯酰胺-丙烯酸钠-十六烷基二甲基烯丙基氯化铵)[P(AM-NaAA-C₁₆DMAAC)]. 聚合物结构经傅里叶变换-红外(FT-IR)光谱和核磁共振碳谱(¹³C NMR)表征证实, 并通过流变性实验研究了微嵌段长度对增粘性能、抗盐性能、粘弹性能的影响规律. 实验结果表明: 该方法可以有效调节缔合聚合物中微嵌段的长度, 随着微嵌段长度增加, 临界缔合浓度(CAC)逐渐降低, 增粘性能、粘弹性能先逐步增加后逐步降低, 并且发现其对聚合物的性能的影响规律中存在最佳嵌段长度.

关键词:

English

Polymerization of Micro-Block Associative Polymer with Alcohol-Surfmer Mixed Micellar Method and Their Rheological Properties

1.
1. State Key Laboratory of Oil and Gas Reservoirs Geology and Exploration, Southwest Petroleum University, Chengdu 610500, P. R. China;
2. School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, P. R. China;
3. Gelogical Scientific Research Institute, Shengli Oilfield Branch Company, SINOPEC, Dongying 257015, Shandong Province, P. R. China
Received Date: 20 February 2012
Available Online: 07 June 2012
Fund Project:
国家科技重大专项(2011ZX05011)资助项目

Abstract:

In this paper, mixed micelle composed of alcohol and polymerizable surfactant (surfmer) were constructed. The aggregated numbers of surfmer (hexadecyl trimethyl allylammonium chloride (C₁₆DMAAC)) in the mixed micelle were measured using a steady-state fluorescence quenching (SSFQ) technique. Using a mixed micellar method with adiabatic polymerization and post-hydrolyzation techniques, the high molecular weight (M_w) micro-block associative polymer of P(AM-NaAA-C₁₆DMAAC) was polymerized. Structures were characterized by Fourier transform-infrared (FT-IR) spectroscopy and ¹³C nuclear magnetic resonance (NMR) spectroscopy. Using rheological experiments, the effects of micro-block length and salt concentration of on the thickening and viscoelastic rheological properties of the polymers were studied. All experiments confirmed that the micro-block length could be adjusted using the mixed micellar method. Increases in the micro-block length were accompanied by decreases in the critical associative concentration (CAC). The viscosities and viscoelastic rheological properties increased to maximum then decreased steady with the length increasing, indicating that the length was at an optimum value.

Key words:

1. [1]
  
  (1) Taylor, K. C.; Nasr-El-Din, H. A. J. Pet. Sci. Eng. 1998, 19, 265.doi: 10.1016/S0920-4105(97)00048-X
  (1) Taylor, K. C.; Nasr-El-Din, H. A. J. Pet. Sci. Eng. 1998, 19, 265.doi: 10.1016/S0920-4105(97)00048-X
2. [2]
  (2) Wever, D. A. Z.; Picchioni, F.; Broekhuis, A. A. Prog. Polym. Sci. 2011, 36, 1558. doi: 10.1016/j.progpolymsci.2011.05.006(2) Wever, D. A. Z.; Picchioni, F.; Broekhuis, A. A. Prog. Polym. Sci. 2011, 36, 1558. doi: 10.1016/j.progpolymsci.2011.05.006
3. [3]
  (3) Volpert, E.; Selb, J.; Candau, F. Macromolecules 1996, 29,1452. doi: 10.1021/ma951178m(3) Volpert, E.; Selb, J.; Candau, F. Macromolecules 1996, 29,1452. doi: 10.1021/ma951178m
4. [4]
  (4) Volpert, E.; Selb, J.; Candau, F. Polymer 1998, 39, 1025. doi: 10.1016/S0032-3861(97)00393-5(4) Volpert, E.; Selb, J.; Candau, F. Polymer 1998, 39, 1025. doi: 10.1016/S0032-3861(97)00393-5
5. [5]
  (5) Stähler, K.; Selb, J.; Candau, F. Langmuir 1999, 15, 7565. doi: 10.1021/la990431z(5) Stähler, K.; Selb, J.; Candau, F. Langmuir 1999, 15, 7565. doi: 10.1021/la990431z
6. [6]
  (6) Thunemann, A. F.; Kubowicz, S.; von Berlepsch, H.; Mohwald,H. Langmuir 2006, 22, 2506. doi: 10.1021/la0533720(6) Thunemann, A. F.; Kubowicz, S.; von Berlepsch, H.; Mohwald,H. Langmuir 2006, 22, 2506. doi: 10.1021/la0533720
7. [7]
  (7) Gao, B. J.; Jiang, L. D.; Kong, D. L. Colloid Polym. Sci. 2007,285, 839. doi: 10.1007/s00396-006-1613-5(7) Gao, B. J.; Jiang, L. D.; Kong, D. L. Colloid Polym. Sci. 2007,285, 839. doi: 10.1007/s00396-006-1613-5
8. [8]
  (8) Unsal, H.; Aydogan, N. Langmuir 2009, 25, 7884. doi: 10.1021/la900456t(8) Unsal, H.; Aydogan, N. Langmuir 2009, 25, 7884. doi: 10.1021/la900456t
9. [9]
  (9) Biggs, S.; Selb, J.; Candau, F. Langmuir 1992, 8, 838. doi: 10.1021/la00039a018(9) Biggs, S.; Selb, J.; Candau, F. Langmuir 1992, 8, 838. doi: 10.1021/la00039a018
10. [10]
  (10) Bu, H.; Kjoniksen, A. L.; Elgsaeter, A.; Nystrom, B. Colloids Surf. A 2006, 278, 166. doi: 10.1016/j.colsurfa.2005.12.016(10) Bu, H.; Kjoniksen, A. L.; Elgsaeter, A.; Nystrom, B. Colloids Surf. A 2006, 278, 166. doi: 10.1016/j.colsurfa.2005.12.016
11. [11]
  (11) Penott-Chang, E. K.; uveia, L.; Fernandez, I. J.; Muller, A. J.;Diaz-Barrios, A.; Saez, A. E. Colloids Surf. A 2007, 295, 99.doi: 10.1016/j.colsurfa.2006.08.038(11) Penott-Chang, E. K.; uveia, L.; Fernandez, I. J.; Muller, A. J.;Diaz-Barrios, A.; Saez, A. E. Colloids Surf. A 2007, 295, 99.doi: 10.1016/j.colsurfa.2006.08.038
12. [12]
  (12) Talwar, S.; Scanu, L.; Raghavan, S. R.; Khan, S. A. Langmuir2008, 24, 7797. doi: 10.1021/la801030n(12) Talwar, S.; Scanu, L.; Raghavan, S. R.; Khan, S. A. Langmuir2008, 24, 7797. doi: 10.1021/la801030n
13. [13]
  (13) Chen, H.; Li, E. X.; Ye, Z. B.; Han, L. J.; Luo, P. Y. Acta Phys. -Chim. Sin. 2011, 27, 671. [陈洪, 李二晓, 叶仲斌,韩利娟, 罗平亚. 物理化学学报, 2011, 27, 671.] doi: 10.3866//PKU.WHXB20110306(13) Chen, H.; Li, E. X.; Ye, Z. B.; Han, L. J.; Luo, P. Y. Acta Phys. -Chim. Sin. 2011, 27, 671. [陈洪, 李二晓, 叶仲斌,韩利娟, 罗平亚. 物理化学学报, 2011, 27, 671.] doi: 10.3866//PKU.WHXB20110306
14. [14]
  (14) Summers, M.; Eastoe, J. Adv. Colloid Interface Sci. 2003,100-102, 137.(14) Summers, M.; Eastoe, J. Adv. Colloid Interface Sci. 2003,100-102, 137.
15. [15]
  (15) Guyot, A. Adv. Colloid Interface Sci. 2004, 108, 3. doi: 10.1016/j.cis.2003.10.009(15) Guyot, A. Adv. Colloid Interface Sci. 2004, 108, 3. doi: 10.1016/j.cis.2003.10.009
16. [16]
  (16) Tajima, K.; Aida, T. Chem. Commun. 2000, 2399.(16) Tajima, K.; Aida, T. Chem. Commun. 2000, 2399.
17. [17]
  (17) Candau, F.; Regalado, E. J.; Selb, J. Macromolecules 1998, 31,5550. doi: 10.1021/ma9802982(17) Candau, F.; Regalado, E. J.; Selb, J. Macromolecules 1998, 31,5550. doi: 10.1021/ma9802982
18. [18]
  (18) Attwood, D.; Mosquera, V.; Rodriguez, J.; Garcia, M.; Suarez,M. J. Colloid & Polymer Science 1994, 272, 584. doi: 10.1007/BF00653225(18) Attwood, D.; Mosquera, V.; Rodriguez, J.; Garcia, M.; Suarez,M. J. Colloid & Polymer Science 1994, 272, 584. doi: 10.1007/BF00653225
19. [19]
  (19) Zhang, X. F.;Wu,W. H. Chin. Chem. Lett. 2009, 20, 1361. doi: 10.1016/j.cclet.2009.06.011(19) Zhang, X. F.;Wu,W. H. Chin. Chem. Lett. 2009, 20, 1361. doi: 10.1016/j.cclet.2009.06.011
20. [20]
  (20) Lianos, P.; Zana, R. Chem. Phys. Lett. 1980, 76, 62. doi: 10.1016/0009-2614(80)80605-1(20) Lianos, P.; Zana, R. Chem. Phys. Lett. 1980, 76, 62. doi: 10.1016/0009-2614(80)80605-1
21. [21]
  (21) Zana, R.; Yiv, S.; Strazielle, C.; Lianos, P. J. Colloid Interface Sci. 1981, 80, 208. doi: 10.1016/0021-9797(81)90177-6(21) Zana, R.; Yiv, S.; Strazielle, C.; Lianos, P. J. Colloid Interface Sci. 1981, 80, 208. doi: 10.1016/0021-9797(81)90177-6
22. [22]
  (22) Zhou, Y. X.; Guo, Y. J.; Luo, P. Y. J. Southwest Pet. Inst. 2004,26, 62. [周云霞, 郭拥军, 罗平亚. 西南石油学院学报, 2004,26, 62.](22) Zhou, Y. X.; Guo, Y. J.; Luo, P. Y. J. Southwest Pet. Inst. 2004,26, 62. [周云霞, 郭拥军, 罗平亚. 西南石油学院学报, 2004,26, 62.]
23. [23]
  (23) Zhang,W. C.; Li, G. Z.; Shen, Q.; Lu, Y. J. Acta Chim. Sin.2000, 58, 374. [张为灿, 李干佐, 沈强, 卢拥军. 化学学报,2000, 58, 374.](23) Zhang,W. C.; Li, G. Z.; Shen, Q.; Lu, Y. J. Acta Chim. Sin.2000, 58, 374. [张为灿, 李干佐, 沈强, 卢拥军. 化学学报,2000, 58, 374.]
24. [24]
  (24) Abdurrahmanoglu, S.; Can, V.; Okay, O. Polymer 2009, 50,5449. doi: 10.1016/j.polymer.2009.09.042(24) Abdurrahmanoglu, S.; Can, V.; Okay, O. Polymer 2009, 50,5449. doi: 10.1016/j.polymer.2009.09.042
25. [25]
  (25) Candau, F.; Selb, J. Adv. Colloid Interface Sci. 1999, 79, 149.doi: 10.1016/S0001-8686(98)00077-3(25) Candau, F.; Selb, J. Adv. Colloid Interface Sci. 1999, 79, 149.doi: 10.1016/S0001-8686(98)00077-3
26. [26]
  (26) Chassenieux, C.; Nicolai, T.; Benyahia, L. Curr. Opin. Colloid Interface Sci. 2011, 16, 18. doi: 10.1016/j.cocis.2010.07.007(26) Chassenieux, C.; Nicolai, T.; Benyahia, L. Curr. Opin. Colloid Interface Sci. 2011, 16, 18. doi: 10.1016/j.cocis.2010.07.007
27. [27]
  (27) Yu, Y. M.;Wang, Z. H.; Gao, B. J.;Wang, R. X. Acta Phys. -Chim. Sin. 2006, 22, 496. [于亚明, 王中华, 高保娇,王蕊欣. 物理化学学报, 2006, 22, 496.] doi: 10.3866/PKU.WHXB20060421(27) Yu, Y. M.;Wang, Z. H.; Gao, B. J.;Wang, R. X. Acta Phys. -Chim. Sin. 2006, 22, 496. [于亚明, 王中华, 高保娇,王蕊欣. 物理化学学报, 2006, 22, 496.] doi: 10.3866/PKU.WHXB20060421
28. [28]
  (28) Kujawa, P.; Audibert-Hayet, A.; Selb, J.; Candau, F.Macromolecules 2006, 39, 384. doi: 10.1021/ma051312v(28) Kujawa, P.; Audibert-Hayet, A.; Selb, J.; Candau, F.Macromolecules 2006, 39, 384. doi: 10.1021/ma051312v
29. [29]
  (29) Regalado, E. J.; Selb, J.; Candau, F. Macromolecules 1999, 32,8580. doi: 10.1021/ma990999e
  (29) Regalado, E. J.; Selb, J.; Candau, F. Macromolecules 1999, 32,8580. doi: 10.1021/ma990999e

扫一扫看文章

计量

PDF下载量: 769
文章访问数: 3058
HTML全文浏览量: 9

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

醇-可聚合表面活性剂混合胶束法合成微嵌段缔合聚合物及其流变性

English

Polymerization of Micro-Block Associative Polymer with Alcohol-Surfmer Mixed Micellar Method and Their Rheological Properties

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

醇-可聚合表面活性剂混合胶束法合成微嵌段缔合聚合物及其流变性

English

Polymerization of Micro-Block Associative Polymer with Alcohol-Surfmer Mixed Micellar Method and Their Rheological Properties

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs