HY分子筛为模板合成的微孔炭及其电化学电容性能

引用本文: 李文, 周晋, 邢伟, 禚淑萍, 吕忆民. HY分子筛为模板合成的微孔炭及其电化学电容性能[J]. 物理化学学报, 2011, 27(03): 620-626. doi: 10.3866/PKU.WHXB20110331 shu

Citation: LI Wen, ZHOU Jin, XING Wei, ZHUO Shu-Ping, Lü Yi-Min. Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance[J]. Acta Physico-Chimica Sinica, 2011, 27(03): 620-626. doi: 10.3866/PKU.WHXB20110331 shu

HY分子筛为模板合成的微孔炭及其电化学电容性能

基金项目:
山东省优秀中青年科学家科研奖励基金(BS2009NJ014) (BS2009NJ014)

山东省科技攻关项目(2009GG10007006)资助 (2009GG10007006)

摘要:

以HY分子筛为模板, 采用糠醇浸渍炭化法和糠醇浸渍-乙腈气相沉积炭化法制备了多种微孔炭材料, 分别标记为PFA系列和AN系列, 并研究了其电化学电容性能. X射线衍射(XRD)测试表明AN系列炭材料较好地复制了HY分子筛模板的孔结构有序性. X射线光电子能谱仪(XPS)测试表明, 乙腈气相沉积在炭材料中引入丰富的含氮官能团. 氮气吸附测试表明, 炭材料是典型的微孔材料, 具有较高的比表面积, 较窄的孔径分布范围. 电化学测试表明, AN系列炭材料电容性能较好, 并具有明显的赝电容, 其中AN8的比电容最大可达210 F·g^-1. AN系列炭材料的电容保持率与材料的导电性和介孔率有关.

关键词:

English

Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance

1.
School of Chemical Engineering, Shandong University of Technology, Zibo 255049, Shandong Province, P. R. China
Received Date: 07 October 2010
Available Online: 03 March 2011
Fund Project:
山东省优秀中青年科学家科研奖励基金(BS2009NJ014)

山东省科技攻关项目(2009GG10007006)资助

Abstract:

Several microporous carbons were prepared by polyfurfuryl alcohol-impregnation and impregnation-acetonitrile chemical vapor deposition (CVD) using zeolite HY as a template, denoted as PFA carbons and AN carbons, respectively. These were used as electrode materials for supercapacitors. X-ray diffraction (XRD) patterns show that the structural regularity of the zeolite was well-replicated by the carbon structures prepared by impregnation-CVD. X-ray photoelectron spectroscopy (XPS) confirmed that the AN carbons possess abundant nitrogen-containing groups because of the CVD of acetonitrile. The prepared carbons were typical microporous materials as determined by N₂ adsorption/desorption test and they had a high BET surface area and narrow pore size distribution. Electrochemical tests showed that the AN carbons had higher capacitance because of their evident pseudo-capacitance from the nitrogen- containing groups. AN8 had a high capacitance up to 210 F·g^-1. The capacitance retention ratio of the AN carbons were determined to its electric conductivity and mesoporosity.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

HY分子筛为模板合成的微孔炭及其电化学电容性能

English

Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

HY分子筛为模板合成的微孔炭及其电化学电容性能

English

Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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