引用本文:
曹立新, 周保学, 史鹏飞, 邹立壮. 四苯硼钾由单-到不同混合溶剂的迁移自由能[J]. 物理化学学报,
2000, 16(11): 1053-1056.
doi:
10.3866/PKU.WHXB20001117
Citation: Cao Li-Xin, Zhou Bao-Xue, Shi Peng-Fei, Zou Li-Zhuang. Standard Tansfer Gibbs Energy of Potassium Tetraphenylborate from Pure Solvents to Solvent Mixtures[J]. Acta Physico-Chimica Sinica, 2000, 16(11): 1053-1056. doi: 10.3866/PKU.WHXB20001117
Citation: Cao Li-Xin, Zhou Bao-Xue, Shi Peng-Fei, Zou Li-Zhuang. Standard Tansfer Gibbs Energy of Potassium Tetraphenylborate from Pure Solvents to Solvent Mixtures[J]. Acta Physico-Chimica Sinica, 2000, 16(11): 1053-1056. doi: 10.3866/PKU.WHXB20001117
English
Standard Tansfer Gibbs Energy of Potassium Tetraphenylborate from Pure Solvents to Solvent Mixtures
Abstract:
The standard transfer Gibbs energy(ΔtrGΘ ) of potassium tetraphenylborate (KBPh4) from water to water and 2-propanol solvent mixtures and from methanol to methanol and 2-propanol solvent mixtures within the whole concentration range of the mixed solvents are studied at 298.15 K. TheΔtrGΘ value of KBPh4 reaches an extreme value from water to water and 2-propanol solvent mixtures, while it increases monotonically with an increasing of 2-propanol content in methanol and 2-propanol solvent mixtures. This indicates the different interaction of KBPh4 with the two kind of solvent mixtures.
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