引用本文:
林慰祯, 沙昆源. dN离子在三角场中的基矢及有关矩阵元[J]. 物理化学学报,
1992, 8(01): 45-51.
doi:
10.3866/PKU.WHXB19920110
Citation: Lin Wei-Zhen, Sha Kun-Yuan. The Basis Vectors of dN Ions in Tri nal Field and Matrix Elements Related[J]. Acta Physico-Chimica Sinica, 1992, 8(01): 45-51. doi: 10.3866/PKU.WHXB19920110
Citation: Lin Wei-Zhen, Sha Kun-Yuan. The Basis Vectors of dN Ions in Tri nal Field and Matrix Elements Related[J]. Acta Physico-Chimica Sinica, 1992, 8(01): 45-51. doi: 10.3866/PKU.WHXB19920110
dN离子在三角场中的基矢及有关矩阵元
摘要:
通过选用合适的单电子基矢, 使按群链[(O?D_3?C_3)×SU(2)]~N构成的多电子基矢, 成为dN体系D_3?C_3旋量群不可约表示的基矢或其两个一维不可约表示直和的基矢。讨论了有关矩阵元和顺磁参数的计算。
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关键词:
- dN组态; 三角配位场; 旋量群
English
The Basis Vectors of dN Ions in Tri nal Field and Matrix Elements Related
Abstract:
By means of the basic vectors matched for group chain ((O?D_3?C_3)×SU(2))~N, the Slater functions of the direct product for single electron can be used as the basis vectors of the irreducible representations of d~N ions or the direct summa-tion representations of two one-dimensional representation. The matrix element ex-pressions related and the calculation of EPR parameters are systematically derived and the corresponding computer programs for all d~N ion in tri nal field have been compiled.
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