自吸式空心针电晕放电离子源的开发及应用

引用本文: 滕科国, 高静, 杨丽丽, 余泉, 王晓浩. 自吸式空心针电晕放电离子源的开发及应用[J]. 分析化学, 2022, 50(8): 1143-1149. doi: 10.19756/j.issn.0253-3820.221094 shu

Citation: TENG Ke-Guo, GAO Jing, YANG Li-Li, YU Quan, WANG Xiao-Hao. Development and Application of Self-aspiration Hollow Needle Corona Discharge Ionization Source[J]. Chinese Journal of Analytical Chemistry, 2022, 50(8): 1143-1149. doi: 10.19756/j.issn.0253-3820.221094 shu

自吸式空心针电晕放电离子源的开发及应用

滕科国 ^1, ,
高静 ^1, ,
杨丽丽 ^2, ,
余泉 ^{1,
,} ,
王晓浩 ^1,

1.
清华大学深圳国际研究生院先进制造学部, 深圳 518055;
2.
燕山大学河北省测试计量技术与仪器重点实验室, 秦皇岛 066004

通讯作者: 余泉,E-mail:yu.quan@sz.tsinghua.edu.cn

基金项目:
国家自然科学基金项目(No.21775085)、河北省重点研发计划项目(No.19275509D)和深圳市基础研究项目(No.JCYJ20180508152013054)资助。

摘要: 搭建了一套自吸式电晕放电离子源,用于挥发性有机物的检测。此离子源结构简单,使用注射器针头作为电晕放电针,利用针头的尖端产生电晕放电,针头中空的结构作为气态样品的传输通路,使样品能高效通过电晕区以提高离子化效率。针尖置于一个密闭的电晕腔体中,腔体与质谱进样接口直接相连,以利用质谱仪的抽气能力进行自吸式进样,同时还能避免周围环境因素对电离过程的影响。另外,此装置还可以搭配注射器针筒使用,方便样品的采集、存储以及自动进样。测试结果表明,所开发的离子源操作方便、响应快、稳定性好,对苯胺检测可以获得nL/L级的检出限,具有较好的应用前景。

关键词:

English

Development and Application of Self-aspiration Hollow Needle Corona Discharge Ionization Source

1.
Division of Advanced Manufacturing, Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, China;
2.
Measurement Technology and Instrumentation Key Lab of Hebei Province, Yanshan University, Qinhuangdao 066004, China

Corresponding author: YU Quan, yu.quan@sz.tsinghua.edu.cn

Received Date: 23 February 2022
Revised Date: 25 April 2022
Fund Project:
Supported by the National Natural Science Foundation of China (No.21775085), the Key Research and Development Program of Hebei Province, China (No.19275509D) and the Fundamental Research Program of Shenzhen, China (No.JCYJ20180508152013054).

Abstract: A self-aspiration corona discharge ionization source was constructed for detection of volatile organic compounds (VOCs). This source had a simple structure that used the tip of a syringe needle to generate the corona discharge. In addition, the hollow needle could also be used as the introduction pathway for the gaseous sample, which allowed the gas to pass through the corona zone efficiently to improve the ionization efficiency. The needle tip was placed in a sealed chamber that was directly connected to the sampling interface of the mass spectrometer. This design could not only utilize the pumping capability of the instrument for self-aspiration sampling, but also avoid the influence of ambient factors on the ionization process. Moreover, the developed hollow needle corona discharge (HNCD) source could be used with a syringe cylinder to facilitate the collection, storage and automatic injection of gas samples. The experimental test results showed that the HNCD source had various merits, including easy operation, fast response and good stability. The detection limit of aniline acquired using this device was at nL/L level, which showed a good application prospect.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

自吸式空心针电晕放电离子源的开发及应用

通讯作者: 余泉,E-mail:yu.quan@sz.tsinghua.edu.cn

English

Development and Application of Self-aspiration Hollow Needle Corona Discharge Ionization Source

Corresponding author: YU Quan, yu.quan@sz.tsinghua.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

自吸式空心针电晕放电离子源的开发及应用

通讯作者: 余泉,E-mail:yu.quan@sz.tsinghua.edu.cn

English

Development and Application of Self-aspiration Hollow Needle Corona Discharge Ionization Source

Corresponding author: YU Quan, yu.quan@sz.tsinghua.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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