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Solvothermal Synthesis, Crystal Structure and Photoluminescence Property of a 3D Lead(II) Coordination Polymer Based on Terephthalic Acid

LIN Xiao-Ying ,  YANG Pan ,  CHEN Jun ,  LIU Ming-Hua ,  LIN Cheng

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Citation:  LIN Xiao-Ying, YANG Pan, CHEN Jun, LIU Ming-Hua, LIN Cheng. Solvothermal Synthesis, Crystal Structure and Photoluminescence Property of a 3D Lead(II) Coordination Polymer Based on Terephthalic Acid[J]. Chinese Journal of Structural Chemistry, 2016, 35(1): 61-68. doi: 10.14102/j.cnki.0254-5861.2011-0948 shu

Solvothermal Synthesis, Crystal Structure and Photoluminescence Property of a 3D Lead(II) Coordination Polymer Based on Terephthalic Acid

  • 1.

    a School of Chemical Engineering, Fuzhou University, Fuzhou 350116, China;

  • 2.

    b College of Ecological Environment and Urban Construction, Fujian University of Technology, Fuzhou 350118, China;

  • 3.

    c College of Environment and Resources, Fuzhou University, Fuzhou 350116, China

  • 基金项目:

    This work was supported by the Natural Science Foundation of Fujian province (2015J01033)  (2015J01033)

    Technology of Fujian Province (2012H6002) (2012H6002)

摘要: Solvothermal reaction of Pb(NO3)2·6H2O with rigid linear ligand terephthalic acid (H2pta) in N,N-dimethylformamide (DMF) produced a new three-dimensional (3D) lead(II) coordination polymer [Pb2(pta)1.5(μ4-OH)(DMF)]n 1, and its structure was characterized by single-crystal X-ray diffraction analyses. In polymer 1, the μ4-OH bridges the nearby lead(II) ions into an infinite one-dimensional (1D) chain, and then the organic ligand pta2- joins the neighbored chains into a 3D structure by two similar connection modes in different configurations. The solid-state photoluminescent studies revealed that 1 exhibits a strong greenish emission mainly originating from ligand-to-metal charge transfer between the delocalized π bonds of the aromatic carboxylate ligand pta2- and the p orbitals of the Pb2+ centers.

English

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  • 收稿日期:  2015-08-18
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