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Two Novel Complexes Based on N-N Bridged Ligand: Syntheses, Crystal Structures, Fluorescence and Magnetic Property

ZHOU Zhong-Yuan ,  XING Xiu-Shuang ,  HAN Yun-Hu ,  TIAN Chong-Bin ,  DU Shao-Wu

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Citation:  ZHOU Zhong-Yuan, XING Xiu-Shuang, HAN Yun-Hu, TIAN Chong-Bin, DU Shao-Wu. Two Novel Complexes Based on N-N Bridged Ligand: Syntheses, Crystal Structures, Fluorescence and Magnetic Property[J]. Chinese Journal of Structural Chemistry, 2016, 35(1): 119-128. doi: 10.14102/j.cnki.0254-5861.2011-0815 shu

Two Novel Complexes Based on N-N Bridged Ligand: Syntheses, Crystal Structures, Fluorescence and Magnetic Property

  • 1.

    a College of Chemistry, Fuzhou University, Fuzhou 350108, China;

  • 2.

    b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;

  • 3.

    c Graduate University of Chinese Academy of Sciences, Beijing 100039, China

    • 通讯作者: TIAN Chong-Bin,
    DU Shao-Wu,
  • 基金项目:

    This project was supported by the National Basic Research Program of China (973 Program, 2012CB821702) (973 Program, 2012CB821702)

摘要: Two novel coordination compounds, 1 [Zn4(L1)4(NO3)2(H2O)2](NO3)2·2H2O and 2 [Mn2(L2)2(DMF)(H2O)3](ClO4)2·DMF (HL1 = N'-[(1E)-pyridine-2-ylmethylidene]pyrazine-2- carbohydrazide, H2L2 = 2-hydroxy-3-methoxybenzaldehyde(pyrazin-2-ylcarbonyl)hydrazone), based on the N-N bridged ligands were prepared and structurally characterized. Compound 1 represents the [2*2] molecular squares, in which both N atoms belonging to the N-N bridged ligands are connected to the Zn centers. The emission of compound 1 exhibits a blue shift, which can be assigned to strong electrostatic interaction between ZnII ions and the L1-1. Compound 2 represents a rare phenol-O bridged Mn2II complex. The magnetic investigation indicates weak antiferromagnetic interactions between the MnII centers.

English

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  • 收稿日期:  2015-05-21
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