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Synthesis, Structure and Polymorphism of a Novel Two-dimensional Cobalt(II) Coordination Polymer Constructed from Citrazinate Ligand

WU Jia-Mei ,  WANG Qi ,  ZENG Li ,  CHEN Yun ,  LIU Ping ,  YI Hai-Bo

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Citation:  WU Jia-Mei, WANG Qi, ZENG Li, CHEN Yun, LIU Ping, YI Hai-Bo. Synthesis, Structure and Polymorphism of a Novel Two-dimensional Cobalt(II) Coordination Polymer Constructed from Citrazinate Ligand[J]. Chinese Journal of Structural Chemistry, 2016, 35(1): 93-99. doi: 10.14102/j.cnki.0254-5861.2011-0809 shu

Synthesis, Structure and Polymorphism of a Novel Two-dimensional Cobalt(II) Coordination Polymer Constructed from Citrazinate Ligand

  • 1.

    a State Key Laboratory of Chemo/biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China;

  • 2.

    b Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

摘要: The polymeric Co(II) complex [Co(Hdhpc)(py)]n (1) (py = pyridine, H3dhpc = 2,6-dihydroxypyridine-4-carboxyl acid) was prepared and characterized. X-ray diffraction data revealed that the compound crystallizes in dimorphic 1α and 1β forms at room and low temperature, respectively. The former crystallizes in the orthorhombic crystal system, space group Pbcm with a = 7.209(1), b = 14.834(3), c = 15.376(3) Å, V = 1644.3(5) Å3, Z = 4, C16H13CoN3O4, Mr = 370.22, Dc = 1.496 g/cm3, F(000) = 756, μ = 1.068 mm-1, R = 0.0633 and wR = 0.1192. While 1β is attributed to the monoclinic space group C2/c with a = 32.102(4), b = 7.022, c = 14.945(2) Å, β = 109.052(5)°, V = 3184.4(6) Å3, Z = 8, Dc = 1.544 g/cm3, F(000) = 1512, μ = 1.103 mm-1, R = 0.0428 and wR = 0.0797. The conformation changes of pyridines between Co-citrazinate planes leading to a reversible single-crystal to single-crystal transformation. The variable temperature magnetic data indicate a weak ferrimagnetism.

English

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