Thiocyanate-controlled Copper(II)-L-arginine Complex: Synthesis, Crystal Structure and Characterization

注册 English

Thiocyanate-controlled Copper(II)-L-arginine Complex: Synthesis, Crystal Structure and Characterization

FAN Guang , DENG Ling-Juan , MA Zhan-Ying , LI Xiao-Bo , ZHANG Yin-Li , SUN Jia-Juan

Citation: FAN Guang, DENG Ling-Juan, MA Zhan-Ying, LI Xiao-Bo, ZHANG Yin-Li, SUN Jia-Juan. Thiocyanate-controlled Copper(II)-L-arginine Complex: Synthesis, Crystal Structure and Characterization[J]. Chinese Journal of Structural Chemistry, 2016, 35(1): 100-106. doi: 10.14102/j.cnki.0254-5861.2011-0804 shu

shu

Thiocyanate-controlled Copper(II)-L-arginine Complex: Synthesis, Crystal Structure and Characterization

1.
College of Chemistry & Chemical Engineering, Xianyang Normal University, Xianyang, Shaanxi 712000, China
基金项目:
Supported by the National Natural Science Foundation of China (No. 21203160) (No. 21203160)

Education Department Foundation of Shaanxi Province (No. 12JK0631) (No. 12JK0631)

Natural Science Foundation of Shaanxi Province (No. 2013JM2013) (No. 2013JM2013)

Special Research Fund of Xianyang Normal University (No. 11XSYK204, 11XSYK205) (No. 11XSYK204, 11XSYK205)

摘要: A novel thiocyanate-controlled copper(II)-L-arginine complex with the formula of Cu(Arg)(SCN)₂ (1, Arg: L-arginine) has been obtained from aqueous solution and structurally characterized by single-crystal X-ray diffraction method. Crystal data: orthorhombic, space group P2₁2₁2₁, a = 6.0156(5), b = 12.1905(11), c = 18.4203(16) Å, V = 1350.8(2) Å³, Z = 4, μ = 1.933 mm^-1, F(000) = 724, S = 1.084, the final R = 0.0410, wR = 0.0754 for 1893 observed reflections with I > 2σ(I), and R = 0.0559, wR = 0.0820 for all reflections. In addition, elemental analysis, IR, TG-DTG and magnetism characterization are presented.

关键词:

English

Thiocyanate-controlled Copper(II)-L-arginine Complex: Synthesis, Crystal Structure and Characterization

1.
College of Chemistry & Chemical Engineering, Xianyang Normal University, Xianyang, Shaanxi 712000, China
Received Date: 11 May 2015
Fund Project:

Abstract: A novel thiocyanate-controlled copper(II)-L-arginine complex with the formula of Cu(Arg)(SCN)₂ (1, Arg: L-arginine) has been obtained from aqueous solution and structurally characterized by single-crystal X-ray diffraction method. Crystal data: orthorhombic, space group P2₁2₁2₁, a = 6.0156(5), b = 12.1905(11), c = 18.4203(16) Å, V = 1350.8(2) Å³, Z = 4, μ = 1.933 mm^-1, F(000) = 724, S = 1.084, the final R = 0.0410, wR = 0.0754 for 1893 observed reflections with I > 2σ(I), and R = 0.0559, wR = 0.0820 for all reflections. In addition, elemental analysis, IR, TG-DTG and magnetism characterization are presented.

Key words:

1. [1]
  (1) Li, J. R.; Sculley, J.; Zhou, H. C. Metal-organic frameworks for separations. Chem. Rev. 2012, 112, 869-932.(1) Li, J. R.; Sculley, J.; Zhou, H. C. Metal-organic frameworks for separations. Chem. Rev. 2012, 112, 869-932.
2. [2]
  (2) Lu, J. Y. Crystal engineering of Cu-containing metal-organic coordination polymers under hydrothermal conditions. Coord. Chem. Rev. 2003, 246, 345-365.(2) Lu, J. Y. Crystal engineering of Cu-containing metal-organic coordination polymers under hydrothermal conditions. Coord. Chem. Rev. 2003, 246, 345-365.
3. [3]
  (3) Du, M.; Li, C. P.; Liu, C. S.; Fang, S. M. Design and construction of coordination polymers with mixed-ligand synthetic strategy. Coord. Chem. Rev. 2013, 257, 1282-1305.(3) Du, M.; Li, C. P.; Liu, C. S.; Fang, S. M. Design and construction of coordination polymers with mixed-ligand synthetic strategy. Coord. Chem. Rev. 2013, 257, 1282-1305.
4. [4]
  (4) Chen, X. M.; Tong, M. L. Solvothermal in-situ metal/ligand reactions: a new bridge between coordination chemistry and organic synthetic chemistry. Acc. Chem. Res. 2007, 40, 162-170.(4) Chen, X. M.; Tong, M. L. Solvothermal in-situ metal/ligand reactions: a new bridge between coordination chemistry and organic synthetic chemistry. Acc. Chem. Res. 2007, 40, 162-170.
5. [5]
  (5) Li, D. S.; Wu, Y. P.; Zhao, J.; Zhang, J.; Lu, J. Y. Metal-organic frameworks based upon non-zeotype 4-connected topology. Coord. Chem. Rev. 2014, 1, 1-27.(5) Li, D. S.; Wu, Y. P.; Zhao, J.; Zhang, J.; Lu, J. Y. Metal-organic frameworks based upon non-zeotype 4-connected topology. Coord. Chem. Rev. 2014, 1, 1-27.
6. [6]
  (6) Bureekaew, S.; Sato, H.; Matsuda, R.; Kubota, Y.; Hirose, R.; Kim, J.; Kato, K.; Takata, M.; Kitagawa, S. Control of interpenetration for tuning structural flexibility influences sorption properties. Angew. Chem. Int. Ed. 2010, 49, 7660-7664.(6) Bureekaew, S.; Sato, H.; Matsuda, R.; Kubota, Y.; Hirose, R.; Kim, J.; Kato, K.; Takata, M.; Kitagawa, S. Control of interpenetration for tuning structural flexibility influences sorption properties. Angew. Chem. Int. Ed. 2010, 49, 7660-7664.
7. [7]
  (7) Yang, S. T.; Choi, S. B.; Sim, J.; Kim, J.; Ahn, W. S. Control of catenation in CuTATB-n metal-organic frameworks by sonochemical synthesis and its effect on CO₂ adsorption. J. Mater. Chem. 2011, 21, 3070-3076.(7) Yang, S. T.; Choi, S. B.; Sim, J.; Kim, J.; Ahn, W. S. Control of catenation in CuTATB-n metal-organic frameworks by sonochemical synthesis and its effect on CO₂ adsorption. J. Mater. Chem. 2011, 21, 3070-3076.
8. [8]
  (8) Fan, G.; Zhang, Y. L.; Zheng, M. Y.; Sun, J. J. Energetic cuprous azide complex: synthesis, crystal structure and effection on the thermal decomposition of HMX. J. Chem. Crystallogr. 2012, 42, 923-927.(8) Fan, G.; Zhang, Y. L.; Zheng, M. Y.; Sun, J. J. Energetic cuprous azide complex: synthesis, crystal structure and effection on the thermal decomposition of HMX. J. Chem. Crystallogr. 2012, 42, 923-927.
9. [9]
  (9) Fan, G.; Zhang, Y. L.; Sun, J. J.; Zheng, M. Y. Energetic cuprous azide complex: synthesis, crystal structure, and characterization. J. Coord. Chem. 2011, 42, 3711-3717.(9) Fan, G.; Zhang, Y. L.; Sun, J. J.; Zheng, M. Y. Energetic cuprous azide complex: synthesis, crystal structure, and characterization. J. Coord. Chem. 2011, 42, 3711-3717.
10. [10]
  (10) Li, D. S.; Zhao, J.; Wu, Y. P.; Liu, B.; Bai, L.; Zou, K.; Du, M. Co₅/Co₈-cluster-based coordination polymers showing high-connected self-penetrating networks: syntheses, crystal structures, and magnetic properties. Inorg. Chem. 2013, 52, 8091-8098.(10) Li, D. S.; Zhao, J.; Wu, Y. P.; Liu, B.; Bai, L.; Zou, K.; Du, M. Co₅/Co₈-cluster-based coordination polymers showing high-connected self-penetrating networks: syntheses, crystal structures, and magnetic properties. Inorg. Chem. 2013, 52, 8091-8098.
11. [11]
  (11) Fan, G.; Zhang, Y. L.; Sun, J. J.; Zheng, M. Y. Synthesis, crystal structure and thermal stability of the coordination polymer [Co(2-mpac)₂(py)·4H₂O)]_n. Chin. J. Struct. Chem. 2012, 31, 250-254.(11) Fan, G.; Zhang, Y. L.; Sun, J. J.; Zheng, M. Y. Synthesis, crystal structure and thermal stability of the coordination polymer [Co(2-mpac)₂(py)·4H₂O)]_n. Chin. J. Struct. Chem. 2012, 31, 250-254.
12. [12]
  (12) Li, D. S.; Zhang, P.; Zhao, J.; Fang, Z. F.; Du, M.; Zou, K.; Mu, Y. Q. Two unique entangling Cd^II-coordination frameworks constructed by square Cd₄ building blocks and auxiliary N,N'-donor ligands. Cryst. Growth Des. 2012, 12, 1697-1702.(12) Li, D. S.; Zhang, P.; Zhao, J.; Fang, Z. F.; Du, M.; Zou, K.; Mu, Y. Q. Two unique entangling Cd^II-coordination frameworks constructed by square Cd₄ building blocks and auxiliary N,N'-donor ligands. Cryst. Growth Des. 2012, 12, 1697-1702.
13. [13]
  (13) Wang, J. J.; Su, Y. C.; Gao, L. J. Syntheses, structures, and photoluminescent properties of two 2D coordination polymers base on 1,3-di(2, 4-dicarboxyphenyl) benzene and 1,3-di(4-pyridyl) propane. Chin. J. Struct. Chem. 2015, 34, 241-247.(13) Wang, J. J.; Su, Y. C.; Gao, L. J. Syntheses, structures, and photoluminescent properties of two 2D coordination polymers base on 1,3-di(2, 4-dicarboxyphenyl) benzene and 1,3-di(4-pyridyl) propane. Chin. J. Struct. Chem. 2015, 34, 241-247.
14. [14]
  (14) Wang, J. J.; Tian, B. N.; Zhao, Z. M.; Hou, X. Y.; Tang, L.; Zhang, M. L. Syntheses, structures, and properties of two new coordination polymers based on tetracarboxylate and 2,2'-bipyridine mixed ligands. Chin. J. Struct. Chem. 2014, 33, 915-920.(14) Wang, J. J.; Tian, B. N.; Zhao, Z. M.; Hou, X. Y.; Tang, L.; Zhang, M. L. Syntheses, structures, and properties of two new coordination polymers based on tetracarboxylate and 2,2'-bipyridine mixed ligands. Chin. J. Struct. Chem. 2014, 33, 915-920.
15. [15]
  (15) Fan, G.; Zhang, Y. L.; Sun, J. J.; Zheng, M. Y. Synthesis, crystal structure and thermal stability of coordination polymer [Co(2-mpac)₂(py)·4H₂O)]_n. Chin. J. Struct. Chem. 2012, 31, 250-254.(15) Fan, G.; Zhang, Y. L.; Sun, J. J.; Zheng, M. Y. Synthesis, crystal structure and thermal stability of coordination polymer [Co(2-mpac)₂(py)·4H₂O)]_n. Chin. J. Struct. Chem. 2012, 31, 250-254.
16. [16]
  (16) Ma, B. Q.; Zhang, D. S.; Gao, S.; Jin, T. Z.; Yan, C. H.; Xu, G. X. From cubane to supercubane: the design, synthesis, and structure of a three-dimensional open framework based on a Ln₄O₄ cluster. Angew. Chem. Int. Ed. 2000, 39, 3644-3646.(16) Ma, B. Q.; Zhang, D. S.; Gao, S.; Jin, T. Z.; Yan, C. H.; Xu, G. X. From cubane to supercubane: the design, synthesis, and structure of a three-dimensional open framework based on a Ln₄O₄ cluster. Angew. Chem. Int. Ed. 2000, 39, 3644-3646.
17. [17]
  (17) Vaidhyanathan, R.; Bradshaw, D.; Rebilly, J. N.; Barrio, J. P.; Gould, J. A.; Berry, N. G.; Rosseinsky, M. J. A family of nanoporous materials based on an amino acid backbone. Angew. Chem. Int. Ed. 2006, 45, 6495-6499.(17) Vaidhyanathan, R.; Bradshaw, D.; Rebilly, J. N.; Barrio, J. P.; Gould, J. A.; Berry, N. G.; Rosseinsky, M. J. A family of nanoporous materials based on an amino acid backbone. Angew. Chem. Int. Ed. 2006, 45, 6495-6499.
18. [18]
  (18) Yamauchi, O.; Odani, A.; Takani, M. Metal-amino acid chemistry: weak interactions and related functions of side chain groups. Dalton Trans. 2002, 3411-3421.(18) Yamauchi, O.; Odani, A.; Takani, M. Metal-amino acid chemistry: weak interactions and related functions of side chain groups. Dalton Trans. 2002, 3411-3421.
19. [19]
  (19) Shimazaki, Y.; Takani, M.; Yamauchi, O. Metal complexes of amino acids and amino acid side chain groups. Structures and properties. Dalton Trans. 2009, 7854-7869.(19) Shimazaki, Y.; Takani, M.; Yamauchi, O. Metal complexes of amino acids and amino acid side chain groups. Structures and properties. Dalton Trans. 2009, 7854-7869.
20. [20]
  (20) Zhao, J. W.; Zhang, J. L.; Li, Y. Z.; Cao, J.; Chen, L. J. Novel one-dimensional organic-inorganic polyoxometalate hybrids constructed from heteropolymolybdate units and copper-aminoacid complexes. Cryst. Growth Des. 2014, 14, 1467-1475.(20) Zhao, J. W.; Zhang, J. L.; Li, Y. Z.; Cao, J.; Chen, L. J. Novel one-dimensional organic-inorganic polyoxometalate hybrids constructed from heteropolymolybdate units and copper-aminoacid complexes. Cryst. Growth Des. 2014, 14, 1467-1475.
21. [21]
  (21) Ashis, K. P.; Tuhin, B.; Sovan, R.; Suryanarayanarao, R.; Akhil, R. C. Copper(II) complexes of L-arginine as netropsin mimics showing DNA cleavage activity in red light. Inorg. Chem. 2009, 48, 2932-2943.(21) Ashis, K. P.; Tuhin, B.; Sovan, R.; Suryanarayanarao, R.; Akhil, R. C. Copper(II) complexes of L-arginine as netropsin mimics showing DNA cleavage activity in red light. Inorg. Chem. 2009, 48, 2932-2943.
22. [22]
  (22) Ou, Z. B.; Lu, Y. H.; Lu, Y. M.; Chen, S.; Xiong, Y. H.; Zhou, X. H.; Mao, Z. W.; Le, X. Y. A copper(II) complex with 2-(2'-pyridyl)benzimidazole and L-arginine: synthesis, structure, antibacterial activities, and DNA interaction. J. Coord. Chem. 2013, 66, 2152-2165.(22) Ou, Z. B.; Lu, Y. H.; Lu, Y. M.; Chen, S.; Xiong, Y. H.; Zhou, X. H.; Mao, Z. W.; Le, X. Y. A copper(II) complex with 2-(2'-pyridyl)benzimidazole and L-arginine: synthesis, structure, antibacterial activities, and DNA interaction. J. Coord. Chem. 2013, 66, 2152-2165.
23. [23]
  (23) Hu, R. X.; Yu, Q.; Liang, F. P.; Ma, L. F.; Chen, X. B.; Zhang, M. B.; Liang, H.; Yu, K. B. Syntheses and crystal structures of cis- and trans-copper(II)complexes of L-arginine. J. Coord. Chem. 2008, 61, 1265-1271.(23) Hu, R. X.; Yu, Q.; Liang, F. P.; Ma, L. F.; Chen, X. B.; Zhang, M. B.; Liang, H.; Yu, K. B. Syntheses and crystal structures of cis- and trans-copper(II)complexes of L-arginine. J. Coord. Chem. 2008, 61, 1265-1271.
24. [24]
  (24) Zivcc, P.; Perdih, F.; Turel, I.; Giester, G.; Psomas, G. Different types of copper complexes with the quinolone antimicrobial drugs ofloxacin and norfloxacin: structure, DNA- and albumin-binding. J. Inorg. Biochem. 2012, 117, 35-47.(24) Zivcc, P.; Perdih, F.; Turel, I.; Giester, G.; Psomas, G. Different types of copper complexes with the quinolone antimicrobial drugs ofloxacin and norfloxacin: structure, DNA- and albumin-binding. J. Inorg. Biochem. 2012, 117, 35-47.
25. [25]
  (25) Sheldrick, G. M. SHELXS-97, Program for Crystal Structure Solution. University of Gottingen, Gottingen, Germany 1997.(25) Sheldrick, G. M. SHELXS-97, Program for Crystal Structure Solution. University of Gottingen, Gottingen, Germany 1997.
26. [26]
  (26) Sheldrick, G. M. SHELXL-97, Program for Crystal Structure Refinement. University of Gottingen, Gottingen, Germany 1997.(26) Sheldrick, G. M. SHELXL-97, Program for Crystal Structure Refinement. University of Gottingen, Gottingen, Germany 1997.
27. [27]
  (27) Hui, R. H.; Zhou, P.; You, Z. L. Syntheses and crystal structures of two end-on thiocyanato-bridged dinuclear copper(II) complexes derived from 2-[(2-ethylaminoethylimino)methyl]phenol and 2,4-dichloro-6-[(2-methylaminoethylimino)methyl]phenol. Synth. React. Inorg., Met.-Org., Nano-Met.Chem. 2009, 39, 495-499.(27) Hui, R. H.; Zhou, P.; You, Z. L. Syntheses and crystal structures of two end-on thiocyanato-bridged dinuclear copper(II) complexes derived from 2-[(2-ethylaminoethylimino)methyl]phenol and 2,4-dichloro-6-[(2-methylaminoethylimino)methyl]phenol. Synth. React. Inorg., Met.-Org., Nano-Met.Chem. 2009, 39, 495-499.
28. [28]
  (28) Shen, L.; Wang, H. T.; Zhang, Y. J.; Jin, Z. M. catena-Poly[[[1,8-bis(2-hydroxyethyl)-1,3,6,8,10,13-hexaazacyclotetra-decane] copper(II)]-l-cyano-[tricyano-nitrosoiron(III)]-l-cyano]. Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 2004, 60, m180-m182.(28) Shen, L.; Wang, H. T.; Zhang, Y. J.; Jin, Z. M. catena-Poly[[[1,8-bis(2-hydroxyethyl)-1,3,6,8,10,13-hexaazacyclotetra-decane] copper(II)]-l-cyano-[tricyano-nitrosoiron(III)]-l-cyano]. Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 2004, 60, m180-m182.
29. [29]
  (29) Mario, W.; Christian, N. In situ solid state formation of copper(I) coordination polymers by thermal reduction of copper(II) precursor compounds: structure and reactivity of [Cu(NCS)₂(pyrimidine)₂]_n. Dalton Trans. 2009, 10192-10198.(29) Mario, W.; Christian, N. In situ solid state formation of copper(I) coordination polymers by thermal reduction of copper(II) precursor compounds: structure and reactivity of [Cu(NCS)₂(pyrimidine)₂]_n. Dalton Trans. 2009, 10192-10198.
30. [30]
  (30) Oksana, V. N.; Anna, V. L.; Svitlana, R. P.; Vladimir, N. K.; Brian, W. S.; Julia, J. Novel 1D and 2D heterometallic Cu/Cd complexes comprising unique mixed-anion Cd(µ-Cl)(µ-O₂CMe)Cl(O₂CMe)^2-, Cd(µ-O₂CMe)I(O₂CMe)^2-, Cd(µ-I)(µ-O₂CMe)I(O₂CMe)^2- and Cd₂(NCS)₆(O₂CMe)₂^2- building blocks: synthesis from elemental copper, structure and magnetism. Polyhedron 2005, 24, 1425-1434.(30) Oksana, V. N.; Anna, V. L.; Svitlana, R. P.; Vladimir, N. K.; Brian, W. S.; Julia, J. Novel 1D and 2D heterometallic Cu/Cd complexes comprising unique mixed-anion Cd(µ-Cl)(µ-O₂CMe)Cl(O₂CMe)^2-, Cd(µ-O₂CMe)I(O₂CMe)^2-, Cd(µ-I)(µ-O₂CMe)I(O₂CMe)^2- and Cd₂(NCS)₆(O₂CMe)₂^2- building blocks: synthesis from elemental copper, structure and magnetism. Polyhedron 2005, 24, 1425-1434.
31. [31]
  (31) Diaz, C.; Ribas, J.; Sanz, N.; Solans, X.; FontBardia, M. Synthesis, crystal structure and magnetic properties of catena-poly [(2,2'-bipyridylcopper)-di-μ-thiocyanato] and bis(2,2'-bipyridyl)thiocyanatocopper(II) perchlorate. Inorg. Chim. Acta 1999, 286, 169-174.(31) Diaz, C.; Ribas, J.; Sanz, N.; Solans, X.; FontBardia, M. Synthesis, crystal structure and magnetic properties of catena-poly [(2,2'-bipyridylcopper)-di-μ-thiocyanato] and bis(2,2'-bipyridyl)thiocyanatocopper(II) perchlorate. Inorg. Chim. Acta 1999, 286, 169-174.
32. [32]
  (32) Oksana, V. P.; Svitlana, R. P.; Volodymyr, N. K.; Brian, W. S.; Oleg, V. S.; Tetyana, S. T. A facile direct synthesis of bimetallic CuIIZnII complexes with ethylenediamine revealing different types of chain crystal structures. Eur. J. Inorg. Chem. 2003, 1426-1432.(32) Oksana, V. P.; Svitlana, R. P.; Volodymyr, N. K.; Brian, W. S.; Oleg, V. S.; Tetyana, S. T. A facile direct synthesis of bimetallic CuIIZnII complexes with ethylenediamine revealing different types of chain crystal structures. Eur. J. Inorg. Chem. 2003, 1426-1432.
33. [33]
  (33) Bernsteinl, J.; Davis, R. E.; Shimoni, L.; Chang, N. L. Patterns in hydrogen bonding: functionality and graph set analysis in crystals. Angew. Chem. Int. Ed. 1995, 34, 1555-1573.(33) Bernsteinl, J.; Davis, R. E.; Shimoni, L.; Chang, N. L. Patterns in hydrogen bonding: functionality and graph set analysis in crystals. Angew. Chem. Int. Ed. 1995, 34, 1555-1573.
34. [34]
  (34) Nakamoto K. Infrared and Raman spectra of inorganic and coordination compounds (4th Ed.)[M]. Wiley Interscience, New York 1986.(34) Nakamoto K. Infrared and Raman spectra of inorganic and coordination compounds (4th Ed.)[M]. Wiley Interscience, New York 1986.

WeChat

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 1039
HTML全文浏览量: 30

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

/

下载: 全尺寸图片幻灯片

分享

用微信扫码二维码

分享至好友和朋友圈