Spectral, Thermal and Structural Studies of Two 3D Coordination Polymers Based on Tetracarboxylic Ligand

Citation: LIANG Li-Li, XU Lei, LI Pei, CHEN Fei-Jian, XUE Hong-Bao. Spectral, Thermal and Structural Studies of Two 3D Coordination Polymers Based on Tetracarboxylic Ligand[J]. Chinese Journal of Structural Chemistry, 2016, 35(1): 85-92. doi: 10.14102/j.cnki.0254-5861.2011-0800 shu

Spectral, Thermal and Structural Studies of Two 3D Coordination Polymers Based on Tetracarboxylic Ligand

1.
a Department of Chemistry, Bengbu Medical College, Bengbu 233030, China;
2.
b State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China
基金项目:
This work was supported by Natural Science Foundation of Anhui Provence (1308085QB24) (1308085QB24)

Anhui Province College Excellent Young Talents Foundation (No. 2013SQRL051ZD) (No. 2013SQRL051ZD)

摘要: Two new coordination polymers, [M₆L₃(DMA)₃(H₂O)] (M = Zn for 1, Cu for 2, L = tetrakis[3-(carboxyphenyl)oxamethyl]methane acid, DMA = N,N-dimethylacetamide) have been solvothermally synthesized. Single-crystal X-ray diffraction analysis reveals that compounds 1 and 2 are isostructural and crystallize in the trigonal space group R3. The asymmetrical unit contains two metal ions, one L⁴^- ligand and two coordinated DMA molecules. The metal ions are connected through six aromatic rings into a linear trimetallic zinc building unit. The whole structure is connected through tetrehedral ligand and the trimetallic building units to form a 4,6-connected framework of the toc topology. Compounds 1 and 2 are further studied by IR spectroscopy, thermogravimetric analyses and PXRD. The solid-state UV-Vis and photoluminescent properties of compounds 1 are also investigated.

关键词:

tetrakis[3-(carboxyphenyl)oxamethyl]methane acid
/ cupper complex
/ cadmium complex
/ luminescent property

English

Spectral, Thermal and Structural Studies of Two 3D Coordination Polymers Based on Tetracarboxylic Ligand

1.
a Department of Chemistry, Bengbu Medical College, Bengbu 233030, China;
2.
b State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China
Received Date: 07 May 2015
Fund Project:

Abstract: Two new coordination polymers, [M₆L₃(DMA)₃(H₂O)] (M = Zn for 1, Cu for 2, L = tetrakis[3-(carboxyphenyl)oxamethyl]methane acid, DMA = N,N-dimethylacetamide) have been solvothermally synthesized. Single-crystal X-ray diffraction analysis reveals that compounds 1 and 2 are isostructural and crystallize in the trigonal space group R3. The asymmetrical unit contains two metal ions, one L⁴^- ligand and two coordinated DMA molecules. The metal ions are connected through six aromatic rings into a linear trimetallic zinc building unit. The whole structure is connected through tetrehedral ligand and the trimetallic building units to form a 4,6-connected framework of the toc topology. Compounds 1 and 2 are further studied by IR spectroscopy, thermogravimetric analyses and PXRD. The solid-state UV-Vis and photoluminescent properties of compounds 1 are also investigated.

Key words:

tetrakis[3-(carboxyphenyl)oxamethyl]methane acid
/ cupper complex
/ cadmium complex
/ luminescent property

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Spectral, Thermal and Structural Studies of Two 3D Coordination Polymers Based on Tetracarboxylic Ligand

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Spectral, Thermal and Structural Studies of Two 3D Coordination Polymers Based on Tetracarboxylic Ligand

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Spectral, Thermal and Structural Studies of Two 3D Coordination Polymers Based on Tetracarboxylic Ligand

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