Structure and Photochemical Properties of a Chiral Cd Coordination Polymer Based on 4,4'-(Hexafluoroisopropylidene) Bis(benzoic acid) and 1,3-Di(pyridineyl)benzene

Citation: WANG Yue-Ming, ZHOU Chun-Hui, XU Tai-Kun HU Jin-Song, XING Hong-Long. Structure and Photochemical Properties of a Chiral Cd Coordination Polymer Based on 4,4'-(Hexafluoroisopropylidene) Bis(benzoic acid) and 1,3-Di(pyridineyl)benzene[J]. Chinese Journal of Structural Chemistry, 2016, 35(1): 129-134. doi: 10.14102/j.cnki.0254-5861.2011-0788 shu

Structure and Photochemical Properties of a Chiral Cd Coordination Polymer Based on 4,4'-(Hexafluoroisopropylidene) Bis(benzoic acid) and 1,3-Di(pyridineyl)benzene

1.
School of Chemical Engineering, Anhui University of Science and Technology, Huainan, Anhui 232001, China
基金项目:
This work was supported by the National Natural Science Foundation of China (No. 51477002, 21301005) (No. 51477002, 21301005)

Natural Science Foundation of Anhui Province (1408085QB31) (1408085QB31)

摘要: One new chiral metal-organic coordination polymer, [Cd₂(dpb)(H₂hfipbb)₂]_n, was obtained under hydrothermal conditions of 1,3-di(pyridineyl)benzene (dpb) and 4,4'-(hexa- fluoroisopropylidene)bis(benzoic acid) (H₂hfipbb). The title compound reveals a three-dimen- sional (3D) framework with two types of helical chains [Cd(COO)]_n, which are linked each other to further form a double helical chain [Cd₂(COO)₂]_n by sharing the same Cd(II) ions. The dpb connects the double helical chains to generate a 3D framework. These unique structures were studied by single-crystal X-ray and other spectroscopy techniques. In addition, the luminescent, fluorescence lifetime and second harmonic generation efficiency properties in the solid state have been studied.

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English

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