聚丙烯腈和二氧化硅复合纤维膜富集-高分辨质谱法测定烟气中的有害化合物

引用本文: 申素素, 梁大鹏, 陈焕文, 苏蕊. 聚丙烯腈和二氧化硅复合纤维膜富集-高分辨质谱法测定烟气中的有害化合物[J]. 分析化学, 2017, 45(2): 253-260. doi: 10.11895/j.issn.0253-3820.160761 shu

Citation: SHEN Su-Su, LIANG Da-Peng, CHEN Huan-Wen, SU Rui. Determination of Hazard Compounds in Cigarette Smoke by High-Resolution Orbitrap Mass Spectrometry Combined with Nanofiber Membrane Extraction[J]. Chinese Journal of Analytical Chemistry, 2017, 45(2): 253-260. doi: 10.11895/j.issn.0253-3820.160761 shu

聚丙烯腈和二氧化硅复合纤维膜富集-高分辨质谱法测定烟气中的有害化合物

1.
吉林大学, 无机合成与制备化学国家重点实验室, 长春 130012;
2.
长春中医药大学, 长春 130117;
3.
吉林大学, 环境与资源学院, 长春 130012;
4.
东华理工大学, 江西省质谱科学与仪器重点实验室, 南昌 330013
基金项目:
本文系吉林省科技厅重点科技攻关项目（No.20160204027YY），吉林省教育厅“十三五”科学技术研究项目（No.2016002）资助

摘要: 以聚丙烯腈（PAN）和二氧化硅（SiO₂）纳米粒子的混合溶液为纺丝溶液，采用静电纺丝技术制备具有高吸附性能的新型PAN-SiO₂疏水性复合纤维膜，对香烟燃烧产生的烟气进行富集，用甲醇作为洗脱溶剂，对待测组分进行洗脱，并使用高分辨串联质谱技术进行测定。实验结果表明，通过调控PAN和SiO₂纳米粒子的浓度，优化静电纺丝参数，得到对小分子有机化合物吸附性较强的纤维膜。对所收集到的烟气进行质谱测定，在正离子模式下，检测到的主要成分有尼古丁、丙酮、苯乙烯、丙烯醛、异戊二烯、丙烯腈等21种小分子有机化合物；在负离子模式下，检测到的主要成分有水杨酸、苹果酸和乳酸等6种有机酸。同时，对烟气中的主要有害成分尼古丁进行定量分析，方法的检出限为0.071 ng/L，定量限为0.236 ng/L。

关键词:

English

Determination of Hazard Compounds in Cigarette Smoke by High-Resolution Orbitrap Mass Spectrometry Combined with Nanofiber Membrane Extraction

1.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China;
2.
Changchun University of Chinese Medicine, Changchun 130117, China;
3.
College of Environment and Resources, Jilin University, Changchun 130012, China;
4.
Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China Institute of Technology, Nanchang 330013, China
Received Date: 14 October 2016
Revised Date: 05 December 2016

Abstract: A new method was proposed for analysis of the organic compounds in cigarette smoke by high resolution Orbitrap mass spectrometry based on polyacrylonitrile-silica (PAN-SiO₂) nanofiber membrane extraction and methanol elution. Hydrophobic PAN-SiO₂ nanofiber membrane which was used to enrich small molecular organic compounds in cigarette smoke was prepared by the technology of electrospinning. Several parameters including the concentrations of PAN and SiO₂ nanopartical, elecrospining voltage, needle aperture and flow rate of spinning solution were optimized. Under the optimal conditions, a PAN-SiO₂ nanofiber membrane with good adsorption performance and great physical strength was obtained. A total of 21 compounds including acetone, styrene, acrolein, isoprene, and acrylonitrile were identified by analyzing the cigarette smoke with Orbitrap MS spectrometry in the positive ion mode. Six organic acids including salicylic acid, malic acid and lactic acid were detected in negative ion mode. The limits of detection and quantification for nicotine were 0.071 ng/L and 0.236 ng/L, respectively.

Key words:

Polyacrylonitrile-silica nanofiber membranes
/ High resolution mass spectrometry
/ Cigarette smoke
/ Hazard organic compounds

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沈阳化工大学材料科学与工程学院沈阳 110142

聚丙烯腈和二氧化硅复合纤维膜富集-高分辨质谱法测定烟气中的有害化合物

English

Determination of Hazard Compounds in Cigarette Smoke by High-Resolution Orbitrap Mass Spectrometry Combined with Nanofiber Membrane Extraction

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

聚丙烯腈和二氧化硅复合纤维膜富集-高分辨质谱法测定烟气中的有害化合物

English

Determination of Hazard Compounds in Cigarette Smoke by High-Resolution Orbitrap Mass Spectrometry Combined with Nanofiber Membrane Extraction

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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