由羧酸和含氮杂环配体构筑从核到双链结构的金属有机骨架

引用本文: 顾晓敏, 王蕾, 单月霞, 张文莉, 陈钦, 倪良, 姚加. 由羧酸和含氮杂环配体构筑从核到双链结构的金属有机骨架[J]. 无机化学学报, 2015, (3): 555-564. doi: 10.11862/CJIC.2015.091 shu

Citation: GU Xiao-Min, WANG Lei, SHAN Yue-Xia, ZHANG Wen-Li, CHEN Qin, NI Liang, YAO Jia. Frameworks of Metal Dicarboxylate Complexes: from Nuclear Structures to Double Chains Based on N-containing Ligands[J]. Chinese Journal of Inorganic Chemistry, 2015, (3): 555-564. doi: 10.11862/CJIC.2015.091 shu

由羧酸和含氮杂环配体构筑从核到双链结构的金属有机骨架

顾晓敏 ^1, ,
王蕾 ^1, ,
单月霞 ^1, ,
张文莉 ^{1,
,} ,
陈钦 ^1, ,
倪良 ^1, ,
姚加 ^2,

1.
1 江苏大学化学化工学院, 镇江 212013;
2.
2 浙江大学化学系, 杭州 310027

通讯作者: 张文莉 zhangwl@ujs.edu.cn

基金项目:
江苏大学高级人才启动基金项目(No.14JDG053) (No.14JDG053)

江苏省博士后科学基金(No.1401176C)资助项目。 (No.1401176C)

摘要: 通过水热法合成了3个配合物{[Mn(4, 4'-oba)(Medpq)]Medpq}_n (1), [Mn₂(4, 4'-oba)₂(MOPIP)₄]·2H₂O (2)和[Cd(ox)(MOPIP)₂]·2H₂O (3)(4, 4'-H₂oba=4, 4'-二苯醚二甲酸, H₂ox=草酸, Medpq=2-甲基吡嗪[3, 2-f:2, 3'-h]喹喔啉, MOPIP=2-(-甲氧基)-氢-咪唑[4, 5-f][1, 10]菲咯啉), 并通过X-射线单晶衍射分析得出它们的晶体结构。配合物1表现为一个一维的双链结构。配合物2和3分别为双核和单核的零维离散结构, 在π-π堆积和氢键的作用下, 进一步形成了三维网络状结构。结构分析结果表明氮杂环和二羧酸配体对配合物的结构有很大影响。此外, 在室温下对配合物2和3进行了荧光性质分析。

关键词:

荧光性质;结构多样性;相互作用;自然键轨道分析

English

Frameworks of Metal Dicarboxylate Complexes: from Nuclear Structures to Double Chains Based on N-containing Ligands

GU Xiao-Min ^1, ,
WANG Lei ^1, ,
SHAN Yue-Xia ^1, ,
ZHANG Wen-Li ^{1,
,} ,
CHEN Qin ^1, ,
NI Liang ^1, ,
YAO Jia ^2,

1.
1 School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China;
2.
2 Department of Chemistry, Zhejiang University, Hangzhou 310027, China

Corresponding author: 张文莉 zhangwl@ujs.edu.cn

Received Date: 01 September 2014
Fund Project:
江苏大学高级人才启动基金项目(No.14JDG053)

江苏省博士后科学基金(No.1401176C)资助项目。

Abstract: Three complexes have been obtained by the reaction of metal (Mn(Ⅱ), Cd(Ⅱ)), 5,6-substituted 1,10-phen derivatives with two carboxylic acids, 4,4'-oxybis(benzoic acid)(4,4'-H₂oba) and oxalic acid (H₂ox). The crystal structures of the resulting complexes, namely {[Mn(4,4'-oba)(Medpq)]Medpq}_n (1), [Mn₂(4,4'-oba)₂(MOPIP)₄]·2H₂O (2), and [Cd(ox)(MOPIP)₂]·2H₂O (3) (Medpq=2-methyldipyrido-[3,2-f:2,3'-h]quinoxaline, MOPIP=2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline]), have been elucidated using their single-crystal X-ray diffraction analysis. Diverse structures are observed for these complexes. Compound 1 contains double chains, which are further stacked via hydrogen bonding interactions to form layers. Compound 2 features dinuclear structures, which are connected by strong π…π and hydrogen bonding interactions to result in layer structures. Compound 3 contains mononuclear structures and extended to chain and layer structures by π…π and hydrogen bonding interactions. The differences among these structures indicate that the size of the rigid chelating ligands and the flexibility of carboxylate have important effects on the structures of their complexes. The fluorescent properties of 2 and 3 were studied in the solid state at room temperature.

Key words:

fluorescent property;structural diversity;interactions;NBO analysis

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沈阳化工大学材料科学与工程学院沈阳 110142

由羧酸和含氮杂环配体构筑从核到双链结构的金属有机骨架

通讯作者: 张文莉 zhangwl@ujs.edu.cn

English

Frameworks of Metal Dicarboxylate Complexes: from Nuclear Structures to Double Chains Based on N-containing Ligands

Corresponding author: 张文莉 zhangwl@ujs.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

由羧酸和含氮杂环配体构筑从核到双链结构的金属有机骨架

通讯作者: 张文莉 zhangwl@ujs.edu.cn

English

Frameworks of Metal Dicarboxylate Complexes: from Nuclear Structures to Double Chains Based on N-containing Ligands

Corresponding author: 张文莉 zhangwl@ujs.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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