Palladium-catalyzed synthesis of 1,2,3,4-tetraalkyl-1,4-diarylbutadienes by cross-coupling of zirconacyclopentadienes with aryl iodides

Hui Wang Jun-Qiu Li Li-Shan Zhou Jun Liu Juan Li Hong-Mei Qu

Citation:  Hui Wang, Jun-Qiu Li, Li-Shan Zhou, Jun Liu, Juan Li, Hong-Mei Qu. Palladium-catalyzed synthesis of 1,2,3,4-tetraalkyl-1,4-diarylbutadienes by cross-coupling of zirconacyclopentadienes with aryl iodides[J]. Chinese Chemical Letters, 2015, 26(10): 1303-1306. doi: 10.1016/j.cclet.2015.06.012 shu

Palladium-catalyzed synthesis of 1,2,3,4-tetraalkyl-1,4-diarylbutadienes by cross-coupling of zirconacyclopentadienes with aryl iodides

    通讯作者: Hong-Mei Qu,
摘要: A novelmethod for the synthesis of 1, 2, 3, 4-tetraalkyl-1, 4-diarylbutadienes was developed via palladiumcatalyzed cross-coupling of zirconacyclopentadienes with aryl iodides. Equivalent of CuCl was introduced to promote the reaction. The desired products were obtained in good to excellent yields and several of them were reported for the first time.

English

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  • 发布日期:  2015-06-17
  • 收稿日期:  2015-04-07
  • 网络出版日期:  2015-05-25
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