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Strategies for synthesizing non-bioaccumulable alternatives to PFOA and PFOS

Min Sha ,  Ping Xing ,  Biao Jiang

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Citation:  Min Sha, Ping Xing, Biao Jiang. Strategies for synthesizing non-bioaccumulable alternatives to PFOA and PFOS[J]. Chinese Chemical Letters, 2015, 26(5): 491-498. doi: 10.1016/j.cclet.2015.03.038 shu

Strategies for synthesizing non-bioaccumulable alternatives to PFOA and PFOS

    • 通讯作者: Biao Jiang,
  • 基金项目:

    This work was supported by the National Natural Science Foundation of China (No. 21102167) (No. 21102167)

    Technology Commission of Shanghai Municipality (No. 12DZ1930902) (No. 12DZ1930902)

摘要: This minireview describes the strategies for synthesis of fluorinated surfactants potentially nonbioaccumulable. Various strategies have been focused on (I) reducing the length of the perfluorocarbon chain, (II) introducing hetero atoms into the fluorocarbon chain, (III) introducing branch (herein and after branch means the fluoro-carbon chain section is not straight). In most cases, the surface tensions versus the surfactant concentrations have been assessed. These above strategies led to various highly fluorinated (perfluorinated or not perfluorinated) surfactants whose chemical changes enabled to obtain novel alternatives to perfluorooctanoic acid (PFOA) and perfluorooctane sulphonate (PFOS).

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  • 发布日期:  2015-04-07
  • 收稿日期:  2015-02-04
  • 网络出版日期:  2015-03-13
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