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β-Octafl uorinated tetrakis(ethoxycarbonyl)porphyrin

Hua-Hua Wang ,  Yi-Yu Jiang ,  Mian HR Mahmood ,  Hai-Yang Liu ,  Herman H.Y. Sung ,  Ian D. Williams ,  Chi K. Chang

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Citation:  Hua-Hua Wang, Yi-Yu Jiang, Mian HR Mahmood, Hai-Yang Liu, Herman H.Y. Sung, Ian D. Williams, Chi K. Chang. β-Octafl uorinated tetrakis(ethoxycarbonyl)porphyrin[J]. Chinese Chemical Letters, 2015, 26(5): 529-533. doi: 10.1016/j.cclet.2015.01.026 shu

β-Octafl uorinated tetrakis(ethoxycarbonyl)porphyrin

    • 通讯作者: Hai-Yang Liu,
    Chi K. Chang,
  • 基金项目:

    This work was supported by National Natural Science Foundation of China (NNSFC) under Grant (Nos. 21171057, 21371059) (NNSFC)

摘要: Tetrakis(alkoxycarbonyl)porphyrin and its β-octafluoro-substituted derivatives were synthesized via Lindsey method and transformed to their zinc complexes. Single crystal X-ray structures of corresponding Zn(II) porphyrins revealed that β-octafluorination will give more compactness of porphyrin moieties in the crystal structure owing to the hydrogen bonding interactions involving bfluorine atoms. An unusual six-coordinated Zn(II) was found via intramolecular coordination of oxygen atom of meso-substituents with central Zn(II).

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  • 发布日期:  2015-01-31
  • 收稿日期:  2014-11-26
  • 网络出版日期:  2015-01-19
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