Synthesis and properties of a novel squaraine dye modified by ferrocene

Yang Wei Huang Nan Yan Fu

引用本文: Yang Wei Huang,  Nan Yan Fu. Synthesis and properties of a novel squaraine dye modified by ferrocene[J]. Chinese Chemical Letters, 2011, 22(11): 1301-1304. doi: 10.1016/j.cclet.2011.05.039 shu
Citation:  Yang Wei Huang,  Nan Yan Fu. Synthesis and properties of a novel squaraine dye modified by ferrocene[J]. Chinese Chemical Letters, 2011, 22(11): 1301-1304. doi: 10.1016/j.cclet.2011.05.039 shu

Synthesis and properties of a novel squaraine dye modified by ferrocene

  • 基金项目:

    The authors are grateful to the National Natural Science Foundation of China (No.20702005) and the Fujian Provincial Natural Science Foundation of China (No.2008J0148).

摘要: A novel squaraine dye (SQ) modified by ferrocene has been synthesized through (E)-l-dodecyl-2-ferrocenyl vinyl-1H-pyrrole and squaric acid. The molecular structure of SQ was characterized by 1H NMR, 13C NMR, MS and elemental analysis. SQ is high soluble in common solvents. The maximum absorptions of SQ in different solvents are in the range of 708-734 nm, exhibiting positive solvatochromism with increasing solvent polarity. The optical and electrical properties of SQ indicate that it is a promising electron donor material for bulk-heterojunction organic solar cell.

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  • 收稿日期:  2011-03-16
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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