引用本文:
Farhad Shirini, Meysam Alipour Khoshdel, Masoumeh Abedini, Seyyed Vahid Atghia. Nanocrystalline TiO2 as an efficient and reusable catalyst for the chemoselective trimethylsilylation of primary and secondary alcohols and phenols[J]. Chinese Chemical Letters,
2011, 22(10): 1211-1214.
doi:
10.1016/j.cclet.2011.05.002
Citation: Farhad Shirini, Meysam Alipour Khoshdel, Masoumeh Abedini, Seyyed Vahid Atghia. Nanocrystalline TiO2 as an efficient and reusable catalyst for the chemoselective trimethylsilylation of primary and secondary alcohols and phenols[J]. Chinese Chemical Letters, 2011, 22(10): 1211-1214. doi: 10.1016/j.cclet.2011.05.002
Citation: Farhad Shirini, Meysam Alipour Khoshdel, Masoumeh Abedini, Seyyed Vahid Atghia. Nanocrystalline TiO2 as an efficient and reusable catalyst for the chemoselective trimethylsilylation of primary and secondary alcohols and phenols[J]. Chinese Chemical Letters, 2011, 22(10): 1211-1214. doi: 10.1016/j.cclet.2011.05.002
Nanocrystalline TiO2 as an efficient and reusable catalyst for the chemoselective trimethylsilylation of primary and secondary alcohols and phenols
摘要:
Nanocrystalline TiO2 was used as an efficient and recyclable catalyst for the chemoselective trimethylsilylation of primary and less hindered secondary alcohols and phenols with hexamethyldisilazane (HMDS). All reactions were performed under mild and completely heterogeneous conditions in good to excellent yields.
English
Nanocrystalline TiO2 as an efficient and reusable catalyst for the chemoselective trimethylsilylation of primary and secondary alcohols and phenols
Abstract:
Nanocrystalline TiO2 was used as an efficient and recyclable catalyst for the chemoselective trimethylsilylation of primary and less hindered secondary alcohols and phenols with hexamethyldisilazane (HMDS). All reactions were performed under mild and completely heterogeneous conditions in good to excellent yields.
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Key words:
- Nanocrystalline TiO2
- / Trimethylsilylation
- / Alcohols
- / Phenols
- / Heterogeneous reaction conditions
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