引用本文:
Tai Ye, Shi Yan Lu, Qin Qin Hu, Xin Jiang, Guo Fen Wei, Jing Jing Wang, Jian Quan Lu. One-bath synthesis of hydrophilic molecularly imprinted quantum dots for selective recognition of chlorophenol[J]. Chinese Chemical Letters,
2011, 22(10): 1253-1256.
doi:
10.1016/j.cclet.2011.03.022
Citation: Tai Ye, Shi Yan Lu, Qin Qin Hu, Xin Jiang, Guo Fen Wei, Jing Jing Wang, Jian Quan Lu. One-bath synthesis of hydrophilic molecularly imprinted quantum dots for selective recognition of chlorophenol[J]. Chinese Chemical Letters, 2011, 22(10): 1253-1256. doi: 10.1016/j.cclet.2011.03.022
Citation: Tai Ye, Shi Yan Lu, Qin Qin Hu, Xin Jiang, Guo Fen Wei, Jing Jing Wang, Jian Quan Lu. One-bath synthesis of hydrophilic molecularly imprinted quantum dots for selective recognition of chlorophenol[J]. Chinese Chemical Letters, 2011, 22(10): 1253-1256. doi: 10.1016/j.cclet.2011.03.022
One-bath synthesis of hydrophilic molecularly imprinted quantum dots for selective recognition of chlorophenol
摘要:
A simple one-bath strategy has been developed to synthesize a novel CdTe@SiO2@MIP (molecularly imprinted and silica-functionalized CdTe quantum dots, MISFQDs), in which a silica shell was coated on the surface of CdTe quantum dots (CdTe@SiO2 QDs) and then a polymer for selective recognition of 4-chlorophenol (4-CP) was constructed on the surface of CdTe@SiO2 QDs using mercaptoacetic acid as stabilizer, 3-aminopropyl-trimethoxysilane (APTES) as functional monomers and tetraethoxysilane (TEOS) as crosslink agent. The structures of CdTe@SiO2@MIP were analyzed by ultraviolet-visible absorption, Fluorescence, FT-IR spectrum and powder X-ray diffraction. The application and characterization of the CdTe@SiO2@MIP were investigated by experiments. All results indicated that the CdTe@SiO2@MIP can selectively recognize 4-chlorophenol.
English
One-bath synthesis of hydrophilic molecularly imprinted quantum dots for selective recognition of chlorophenol
Abstract:
A simple one-bath strategy has been developed to synthesize a novel CdTe@SiO2@MIP (molecularly imprinted and silica-functionalized CdTe quantum dots, MISFQDs), in which a silica shell was coated on the surface of CdTe quantum dots (CdTe@SiO2 QDs) and then a polymer for selective recognition of 4-chlorophenol (4-CP) was constructed on the surface of CdTe@SiO2 QDs using mercaptoacetic acid as stabilizer, 3-aminopropyl-trimethoxysilane (APTES) as functional monomers and tetraethoxysilane (TEOS) as crosslink agent. The structures of CdTe@SiO2@MIP were analyzed by ultraviolet-visible absorption, Fluorescence, FT-IR spectrum and powder X-ray diffraction. The application and characterization of the CdTe@SiO2@MIP were investigated by experiments. All results indicated that the CdTe@SiO2@MIP can selectively recognize 4-chlorophenol.
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