Carbamate synthesis from amines and dialkyl carbonate over inexpensive and clean acidic catalyst-Sulfamic acid

Bo Wang Jing He Run Cang Sun

引用本文: Bo Wang,  Jing He,  Run Cang Sun. Carbamate synthesis from amines and dialkyl carbonate over inexpensive and clean acidic catalyst-Sulfamic acid[J]. Chinese Chemical Letters, 2010, 21(7): 794-797. doi: 10.1016/j.cclet.2010.03.012 shu
Citation:  Bo Wang,  Jing He,  Run Cang Sun. Carbamate synthesis from amines and dialkyl carbonate over inexpensive and clean acidic catalyst-Sulfamic acid[J]. Chinese Chemical Letters, 2010, 21(7): 794-797. doi: 10.1016/j.cclet.2010.03.012 shu

Carbamate synthesis from amines and dialkyl carbonate over inexpensive and clean acidic catalyst-Sulfamic acid

  • 基金项目:

    Financial supports from the Beijing Forestry University Excellent Young Scientist Fund (No. BLYX200904), National Innovation Experiment Program for University Students (No. 091002234) and Major State Basic Research Development Program of China (973 Program, No. 2010CB732204) are gratefully acknowledged. We wish to thank Prof. Run-Hua Lu and Prof. Li-Ming Yang for much useful criticism during the preparation of this paper and for many interesting and helpful discussions.

摘要: Sulfamic acid has been proved to be the most efficient and recyclable catalyst in carbamate synthesis from alkylamine and dialkyl carbonate. High selectivity, cost-efficiency and simple product separation were the advantageous features obtained in this process. Sulfamic acid could be reused several times and keep its initial activity in the recycle runs. In addition, sulfamic acid has also exhibited the potential catalytic ability for alkylation of aromatic amines.

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  • 收稿日期:  2009-11-06
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