A facile synthesis of 2,4,6-trichloroborazine from boron trichloride-dimethylsulfide complex and ammonium chloride

Cheng Deng Yong Cai Song Ying De Wang Yi He Li Yong Peng Lei Shu Wei Cao

引用本文: Cheng Deng,  Yong Cai Song,  Ying De Wang,  Yi He Li,  Yong Peng Lei,  Shu Wei Cao. A facile synthesis of 2,4,6-trichloroborazine from boron trichloride-dimethylsulfide complex and ammonium chloride[J]. Chinese Chemical Letters, 2010, 21(2): 135-138. doi: 10.1016/j.cclet.2009.10.016 shu
Citation:  Cheng Deng,  Yong Cai Song,  Ying De Wang,  Yi He Li,  Yong Peng Lei,  Shu Wei Cao. A facile synthesis of 2,4,6-trichloroborazine from boron trichloride-dimethylsulfide complex and ammonium chloride[J]. Chinese Chemical Letters, 2010, 21(2): 135-138. doi: 10.1016/j.cclet.2009.10.016 shu

A facile synthesis of 2,4,6-trichloroborazine from boron trichloride-dimethylsulfide complex and ammonium chloride

  • 基金项目:

    We wish to thank the National "863" Program (No. 2006AA03A217) for financial support of the research.

摘要: 2,4,6-Trichloroborazine has been recognized as a desirable monomer for the preparation of high-performance boron nitride fibers through polymer derived ceramics route.So a high yield and facile synthesis of 2,4,6-trichloroborazine is essential in practice.Using boron trichloride-dimethylsulfide complex((CH3)2S·BCl3)and ammonium chloride(NH4Cl)as starting materials and toluene(C6H5CH3)as solvent,the synthesis of 2,4,6-trichloroborazine to give high yield is reported.(C)2009 Cheng Deng.Published by Elsevier B.V.on behalf of Chinese Chemical Society.All rights reserved.

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  • 收稿日期:  2009-06-02
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