引用本文:
Chun Hua Ge, Xiang Dong Zhang, Yong Chao Ma, Lei Guan, Chun Yue Shi, Xiao Yan Zhang, Ya Nan Guo, Qi Tao Liu. Gear-like array of (H2O)12 as building blocks in one-dimensional supramolecular assembly[J]. Chinese Chemical Letters,
2007, 18(11): 1389-1391.
doi:
10.1016/j.cclet.2007.07.015
Citation: Chun Hua Ge, Xiang Dong Zhang, Yong Chao Ma, Lei Guan, Chun Yue Shi, Xiao Yan Zhang, Ya Nan Guo, Qi Tao Liu. Gear-like array of (H2O)12 as building blocks in one-dimensional supramolecular assembly[J]. Chinese Chemical Letters, 2007, 18(11): 1389-1391. doi: 10.1016/j.cclet.2007.07.015
Citation: Chun Hua Ge, Xiang Dong Zhang, Yong Chao Ma, Lei Guan, Chun Yue Shi, Xiao Yan Zhang, Ya Nan Guo, Qi Tao Liu. Gear-like array of (H2O)12 as building blocks in one-dimensional supramolecular assembly[J]. Chinese Chemical Letters, 2007, 18(11): 1389-1391. doi: 10.1016/j.cclet.2007.07.015
Gear-like array of (H2O)12 as building blocks in one-dimensional supramolecular assembly
摘要:
The prepartion crystal structure of complex Co (Hsae)2·2H2O (1, H2sae=N-salicylidene-2-iminoethanol) are reported X-ray analysis revealed that every six Co (Hsae)2 forms a cyclic chip and every 12 water forms a novel gear-like cluster. Acting as building blocks, the gear-like water cluster and complex chip are connected in A-B fashion and extend into one-dimensional supramolecular chain. Hydrogen bond is the primary bridging force in the formation of supramolecular framework.
English
Gear-like array of (H2O)12 as building blocks in one-dimensional supramolecular assembly
Abstract:
The prepartion crystal structure of complex Co (Hsae)2·2H2O (1, H2sae=N-salicylidene-2-iminoethanol) are reported X-ray analysis revealed that every six Co (Hsae)2 forms a cyclic chip and every 12 water forms a novel gear-like cluster. Acting as building blocks, the gear-like water cluster and complex chip are connected in A-B fashion and extend into one-dimensional supramolecular chain. Hydrogen bond is the primary bridging force in the formation of supramolecular framework.
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