引用本文:
Zhi Huan Weng, Jin Yan Wang, Xi Gao Jian. Efficient oxidation of benzyl alcohol with heteropolytungstate as reaction-controlled phase-transfer catalyst[J]. Chinese Chemical Letters,
2007, 18(8): 936-938.
doi:
10.1016/j.cclet.2007.06.007
Citation: Zhi Huan Weng, Jin Yan Wang, Xi Gao Jian. Efficient oxidation of benzyl alcohol with heteropolytungstate as reaction-controlled phase-transfer catalyst[J]. Chinese Chemical Letters, 2007, 18(8): 936-938. doi: 10.1016/j.cclet.2007.06.007
Citation: Zhi Huan Weng, Jin Yan Wang, Xi Gao Jian. Efficient oxidation of benzyl alcohol with heteropolytungstate as reaction-controlled phase-transfer catalyst[J]. Chinese Chemical Letters, 2007, 18(8): 936-938. doi: 10.1016/j.cclet.2007.06.007
Efficient oxidation of benzyl alcohol with heteropolytungstate as reaction-controlled phase-transfer catalyst
摘要:
A series of heteropolytungstates has been synthesized and utilized as catalysts to catalyze oxidation of benzyl alcohol with aqueous hydrogen peroxide. The results indicated that three of these catalysts showed the properties of reaction-controlled phasetransfer catalysis, and they had excellent catalytic ability to the oxidation of benzyl alcohol. No other by-products were detected by gas chromatography. Once the hydrogen peroxide was consumed completely, the catalyst precipitated from solvent, and the results of the catalyst recycle showed that the catalyst had high stability.
English
Efficient oxidation of benzyl alcohol with heteropolytungstate as reaction-controlled phase-transfer catalyst
Abstract:
A series of heteropolytungstates has been synthesized and utilized as catalysts to catalyze oxidation of benzyl alcohol with aqueous hydrogen peroxide. The results indicated that three of these catalysts showed the properties of reaction-controlled phasetransfer catalysis, and they had excellent catalytic ability to the oxidation of benzyl alcohol. No other by-products were detected by gas chromatography. Once the hydrogen peroxide was consumed completely, the catalyst precipitated from solvent, and the results of the catalyst recycle showed that the catalyst had high stability.
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