Synthesis and characterization of biodegradable aliphatic polyesters using dibutylmagnesium as initiator

Lian Liu Zhi Yong Wei Min Qi

引用本文: Lian Liu,  Zhi Yong Wei,  Min Qi. Synthesis and characterization of biodegradable aliphatic polyesters using dibutylmagnesium as initiator[J]. Chinese Chemical Letters, 2007, 18(6): 744-746. doi: 10.1016/j.cclet.2007.04.011 shu
Citation:  Lian Liu,  Zhi Yong Wei,  Min Qi. Synthesis and characterization of biodegradable aliphatic polyesters using dibutylmagnesium as initiator[J]. Chinese Chemical Letters, 2007, 18(6): 744-746. doi: 10.1016/j.cclet.2007.04.011 shu

Synthesis and characterization of biodegradable aliphatic polyesters using dibutylmagnesium as initiator

  • 基金项目:

    This work was supported by the National Natural Science Foundation of China (No. 30470521).

摘要: Aliphatic polyesters were synthesized via the ring opening polymerization of the corresponding lactones initiated with dibutylmagnesium both in bulk and in solution.The resulting polymers were characterized by 1H, 13C NMR, GPC and XRD.The results indicated that dibutylmagnesium is an effective initiator for the ring opening polymerization of lactones.

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  • 收稿日期:  2007-01-22
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