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离子液体催化甘油和尿素合成甘油碳酸酯

陈娟娟 ,  王畅 ,  董彬 ,  冷文光 ,  黄军 ,  格日乐 ,  高艳安

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引用本文: 陈娟娟, 王畅, 董彬, 冷文光, 黄军, 格日乐, 高艳安. 离子液体催化甘油和尿素合成甘油碳酸酯[J]. 催化学报, 2015, 36(3): 336-343. doi: 10.1016/S1872-2067(14)60257-6 shu
Citation:  Juanjuan Chen, Chang Wang, Bin Dong, Wenguang Leng, Jun Huang, Rile Ge, Yanan Gao. Ionic liquids as eco-friendly catalysts for converting glycerol and urea into high value-added glycerol carbonate[J]. Chinese Journal of Catalysis, 2015, 36(3): 336-343. doi: 10.1016/S1872-2067(14)60257-6 shu

离子液体催化甘油和尿素合成甘油碳酸酯

    通讯作者: 黄 军, 高艳安
  • 基金项目:

    国家自然科学基金(21273235, 21303076) (21273235, 21303076)

    中国科学院"百人计划". 

摘要: 将一系列酸性、碱性和中性的功能化离子液体用于催化甘油和尿素合成甘油碳酸酯.结果表明, 中性离子液体表现出更高的催化活性.离子液体阳离子和阴离子的协同效应促进了反应的进行, 离子液体阳离子的正电性活化尿素, 阴离子的负电性活化甘油, 并且催化剂酸碱位点的平衡对催化反应过程也有一定的影响.此外, 离子液体可以实现回收利用至少五次, 且催化活性基本不变.采用功能化离子液体替代传统金属催化剂, 减少了不可再生资源的利用, 且所用原料为廉价易得的生物基原料, 过程中也不使用有机溶剂, 环境友好.

English

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  • 发布日期:  2015-03-20
  • 收稿日期:  2014-10-16
  • 网络出版日期:  2014-11-19
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