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微波法制备还原氧化石墨烯负载Pt3Co纳米合金

石娟娟 ,  聂仁峰 ,  张梦媛 ,  赵梦思 ,  侯昭胤

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引用本文: 石娟娟, 聂仁峰, 张梦媛, 赵梦思, 侯昭胤. 微波法制备还原氧化石墨烯负载Pt3Co纳米合金[J]. 催化学报, 2014, 35(12): 2029-2037. doi: 10.1016/S1872-2067(14)60232-1 shu
Citation:  Juanjuan Shi, Renfeng Nie, Mengyuan Zhang, Mengsi Zhao, Zhaoyin Hou. Microwave-assisted fast fabrication of a nanosized Pt3Co alloy on reduced graphene oxides[J]. Chinese Journal of Catalysis, 2014, 35(12): 2029-2037. doi: 10.1016/S1872-2067(14)60232-1 shu

微波法制备还原氧化石墨烯负载Pt3Co纳米合金

    通讯作者: 侯昭胤
  • 基金项目:

    国家自然科学基金(21473155, 21273198, 21073159) (21473155, 21273198, 21073159)

    浙江省自然科学基金(L12B03001). (L12B03001)

摘要: 微波辐射法可以在数分钟内将高度分散的 Pt3Co 合金颗粒负载于还原氧化石墨烯表面上.表征结果发现, 与传统的溶剂热法和浸渍法相比,微波法制备的催化剂中贵金属的利用率高, 合金颗粒的分布均匀, 组成可控, 同时氧化石墨烯的再石墨化现象也得到有效地抑制.采用微波法制备的Pt3Co/RGO-MW催化剂在肉桂醛加氢反应中具有较高的活性和和产物选择性. Pt3Co/RGO-MW中每一个 Pt 原子在70 ℃的转化频率高达23.8 min-1.

English

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  • 收稿日期:  2014-07-30
  • 网络出版日期:  2014-09-30
通讯作者: 陈斌, bchen63@163.com
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