纳米磁性固体酸SO42-/Zr(OH)4-Fe3O4催化水相不对称Aldol反应

引用本文: 邬涛, 万敬伟, 马学兵. 纳米磁性固体酸SO₄^2-/Zr(OH)₄-Fe₃O₄催化水相不对称Aldol反应[J]. 催化学报, 2015, 36(3): 425-431. doi: 10.1016/S1872-2067(14)60222-9 shu

Citation: Tao Wu, Jingwei Wan, Xuebing Ma. Aqueous asymmetric aldol reaction catalyzed by nanomagnetic solid acid SO₄^2-/Zr(OH)₄-Fe₃O₄[J]. Chinese Journal of Catalysis, 2015, 36(3): 425-431. doi: 10.1016/S1872-2067(14)60222-9 shu

纳米磁性固体酸SO₄^2-/Zr(OH)₄-Fe₃O₄催化水相不对称Aldol反应

通讯作者: 马学兵

基金项目:
国家自然科学基金(21071116). (21071116)

摘要: 以纳米磁性材料Fe₃O₄, ZrOCl₂·8H₂O和硫酸为原料, 在不同焙烧温度下制备了纳米磁性固体酸催化剂SO₄^2-/Zr(OH)₄-Fe₃O₄.详细表征了该磁性固体酸的SO₄^2-负载量、酸分布、表面形貌和孔结构等特性.在含有硝基和氰基强吸电子基苯甲醛的不对称水相Aldol反应中, SO₄^2-/Zr(OH)₄-Fe₃O₄表现出优良的催化性能(83%-100%收率, 86.0%-95.6% ee anti和anti/syn = 88-96/12-4).该类磁性固体酸可在外加磁体作用下定量地从催化反应体系中分离并回收使用, 重复使用5次未见显著失活.

关键词:

English

Aqueous asymmetric aldol reaction catalyzed by nanomagnetic solid acid SO₄^2-/Zr(OH)₄-Fe₃O₄

1.
School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China

Corresponding author: 马学兵

Received Date: 13 July 2014
Available Online: 20 March 2015
Fund Project:
国家自然科学基金(21071116).

Abstract: Magnetic solid acid catalysts SO₄^2-/Zr(OH)₄-Fe₃O₄ were prepared using magnetic Fe₃O₄ nanoparticles, ZrOCl₂·8H₂O, and sulfuric acid as starting materials in the calcination temperature range 110-650 ℃. The properties of the magnetic solid acid, such as loaded SO₄^2- content, acid distribution, surface morphology, and porous structure, were characterized. In the aqueous asymmetric aldol reaction of various benzaldehydes with strong electron-withdrawing groups (R=NO₂ and CN), good to excellent catalytic performance (83%-100% yield, 86.0%-95.6% ee anti, and anti/syn=88-96/12-4) was achieved. These nanomagnetic solid acids can be quantitatively recycled from the reaction mixture using an external magnet and reused five times without significant loss of catalytic activity.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

纳米磁性固体酸SO₄^2-/Zr(OH)₄-Fe₃O₄催化水相不对称Aldol反应

通讯作者: 马学兵

English

Aqueous asymmetric aldol reaction catalyzed by nanomagnetic solid acid SO₄^2-/Zr(OH)₄-Fe₃O₄

Corresponding author: 马学兵

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