Cu-Ni双金属催化剂催化脂肪伯醇脱氢制备醛

引用本文: 芦天亮, 杜中田, 刘俊霞, 陈晨, 徐杰. Cu-Ni双金属催化剂催化脂肪伯醇脱氢制备醛[J]. 催化学报, 2014, 35(12): 1911-1916. doi: 10.1016/S1872-2067(14)60208-4 shu

Citation: Tianliang Lu, Zhongtian Du, Junxia Liu, Chen Chen, Jie Xu. Dehydrogenation of primary aliphatic alcohols to aldehydes over Cu-Ni bimetallic catalysts[J]. Chinese Journal of Catalysis, 2014, 35(12): 1911-1916. doi: 10.1016/S1872-2067(14)60208-4 shu

Cu-Ni双金属催化剂催化脂肪伯醇脱氢制备醛

芦天亮 ^a,b, ,
杜中田 ^a, ,
刘俊霞 ^a,b, ,
陈晨 ^a, ,
徐杰 ^{a,
,}

通讯作者: 徐杰

基金项目:
国家自然科学基金(21203180和21233008). (21203180和21233008)

摘要: 脂肪伯醇催化转化制备相应的醛是具有挑战性的课题, 目前多采用负载的单金属铜基催化剂. 本文报道了双金属催化剂Cu-Ni/γ-Al₂O₃催化3,3-二甲基-1-丁醇脱氢制备相应的醛, 在相同反应条件下, Cu-Ni/γ-Al₂O₃比单金属催化剂Cu/γ-Al₂O表现出更高的催化活性, 能将一系列脂肪伯醇高选择性转化为相应的醛.

关键词:

脂肪伯醇
/ 醛
/ 铜-镍
/ 催化
/ 脱氢

English

Dehydrogenation of primary aliphatic alcohols to aldehydes over Cu-Ni bimetallic catalysts

1.
a. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: 徐杰

Received Date: 27 June 2014
Fund Project:
国家自然科学基金(21203180和21233008).

Abstract: The catalytic conversion of non-activated primary aliphatic alcohols to aldehydes is a challenge, and monometallic Cu-based catalysts loaded on different supports have often been used for these reactions. Cu-Ni/γ-Al₂O₃ bimetallic catalysts were prepared and used for anaerobic dehydrogenation of 3,3-dimethyl-1-butanol to 3,3-dimethyl-1-butanal. These catalysts exhibited higher activity than Cu/γ-Al₂O₃ under the same reaction conditions, and a wide range of primary aliphatic alcohols were efficiently converted to the corresponding aldehydes over Cu-Ni/γ-Al₂O₃ under mild conditions.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Cu-Ni双金属催化剂催化脂肪伯醇脱氢制备醛

通讯作者: 徐杰

English

Dehydrogenation of primary aliphatic alcohols to aldehydes over Cu-Ni bimetallic catalysts

Corresponding author: 徐杰

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Cu-Ni双金属催化剂催化脂肪伯醇脱氢制备醛

通讯作者: 徐杰

English

Dehydrogenation of primary aliphatic alcohols to aldehydes over Cu-Ni bimetallic catalysts

Corresponding author: 徐杰

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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