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海蛎壳粉废弃物负载CuCl2作为高效、廉价以及可回收催化剂合成炔胺类化合物

熊兴泉 ,  陈会新 ,  朱荣俊

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引用本文: 熊兴泉, 陈会新, 朱荣俊. 海蛎壳粉废弃物负载CuCl2作为高效、廉价以及可回收催化剂合成炔胺类化合物[J]. 催化学报, 2014, 35(12): 2006-2013. doi: 10.1016/S1872-2067(14)60195-9 shu
Citation:  Xingquan Xiong, Huixin Chen, Rongjun Zhu. Oyster shell waste supported CuCl2 for aldehyde-alkyne-amine coupling reaction to propargylamines[J]. Chinese Journal of Catalysis, 2014, 35(12): 2006-2013. doi: 10.1016/S1872-2067(14)60195-9 shu

海蛎壳粉废弃物负载CuCl2作为高效、廉价以及可回收催化剂合成炔胺类化合物

    通讯作者: 熊兴泉
  • 基金项目:

    国家自然科学基金(21004024) (21004024)

    福建省自然科学基金(2011J01046) (2011J01046)

    福建省“高校新世纪优秀人才支持计划”(2012FJ-NCET-ZR03) (2012FJ-NCET-ZR03)

    福建省“高校杰出青年科研人才培育计划”(11FJPY02) (11FJPY02)

    “华侨大学中青年教师科研提升资助计划” (ZQN-YX103). (ZQN-YX103)

摘要: 发展了一种经济、简单的海蛎壳粉负载的CuCl2异相催化剂OSP-CuCl2, 用来催化醛-炔-胺之间的A3偶联反应.OSP-CuCl2容易通过简单的方法从海蛎壳粉以及CuCl2制备, 且显示出高的催化活性以及良好的可循环回收性.在微波辅助以及无溶剂条件下, 以OSP-CuCl2为催化剂, 能够以高产物收率制备出一系列炔胺类化合物.OSP-CuCl2可通过简单的过滤方式进行回收, 并至少可循环使用6次.初步放大实验表明, 炔胺类化合物能够以150 mmol的规模制备(87%收率).

English

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  • 收稿日期:  2014-06-08
  • 网络出版日期:  2014-07-17
通讯作者: 陈斌, bchen63@163.com
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