氨功能化陶瓷膜支撑体担载钯纳米颗粒及其增强的催化性能

引用本文: 姜红, 孙晓旭, 杜艳, 陈日志, 邢卫红. 氨功能化陶瓷膜支撑体担载钯纳米颗粒及其增强的催化性能[J]. 催化学报, 2014, 35(12): 1990-1996. doi: 10.1016/S1872-2067(14)60190-X shu

Citation: Hong Jiang, Xiaoxu Sun, Yan Du, Rizhi Chen, Weihong Xing. Catalytic activity of palladium nanoparticles immobilized on an amino-functionalized ceramic membrane support[J]. Chinese Journal of Catalysis, 2014, 35(12): 1990-1996. doi: 10.1016/S1872-2067(14)60190-X shu

氨功能化陶瓷膜支撑体担载钯纳米颗粒及其增强的催化性能

姜红 ^a, ,
孙晓旭 ^a, ,
杜艳 ^b, ,
陈日志 ^{a,
,} ,
邢卫红 ^{a,
,}

通讯作者: 陈日志, 邢卫红; 陈日志, 邢卫红

基金项目:
国家自然科学基金(21106061, 21125629) (21106061, 21125629)

江苏省自然科学基金(BK20130920). (BK20130920)

摘要: 采用双氨基硅烷偶联剂N-β-(氨乙基)-γ-氨丙基三甲氧基硅烷(AAPTS)对陶瓷膜表面接枝功能化并负载钯纳米颗粒, 制得一种有效的可重复使用的催化剂.利用X射线衍射、扫描电镜、电子能谱、感应耦合等离子体、X射线光电子能谱和高分辨透射电镜对催化剂进行了物性表征, 并将其用于催化对硝基苯酚加氢制对氨基苯酚反应.和单氨基硅烷g-氨丙基三乙氧基硅烷(3-APTS)功能化改性相比, 担载在AAPTS功能化陶瓷膜上的钯纳米颗粒具有更高的催化活性和稳定性.相比于3-APTS, AAPTS分子中含有两个氨基, 具有更强的供电子效应, 因此钯纳米颗粒可更多更稳定地负载在AAPTS功能化陶瓷膜上, 从而具有更高的催化活性和稳定性.

关键词:

English

Catalytic activity of palladium nanoparticles immobilized on an amino-functionalized ceramic membrane support

Hong Jiang ^a, ,
Xiaoxu Sun ^a, ,
Yan Du ^b, ,
Rizhi Chen ^{a,
,} ,
Weihong Xing ^{a,
,}

1.
a. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, Jiangsu, China;

Corresponding author: 陈日志, 邢卫红; 陈日志, 邢卫红

Received Date: 22 May 2014
Fund Project:
国家自然科学基金(21106061, 21125629)

江苏省自然科学基金(BK20130920).

Abstract: Pd nanoparticles were immobilized on a tubular ceramic membrane support. The support surface was functionalized by N-(β-aminoethyl)-γ-aminopropyl trimethoxy silane (AAPTS), which contains two amino groups. The Pd-immobilized ceramic membrane support was characterized by X-ray diffraction, field-emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, inductively coupled plasma emission spectroscopy, X-ray photoelectron spectroscopy, and high-resolution transmission electron microscopy. Its catalytic properties were investigated by the liquid phase hydrogenation of p-nitrophenol to p-aminophenol. The Pd-immobilized ceramic membrane support was compared with the Pd nanoparticles immobilized on a similar support functionalized by γ-amino-propyltriethoxy silane (3-APTS), which contains one amino group. Higher catalytic activity and stability were observed for the AAPTS-functionalized support. AAPTS contains twice as many amino groups as 3-APTS, and consequently exhibited a stronger electron-donating effect toward Pd. The AAPTS-functionalized ceramic membrane support contained more immobilized Pd nanoparticles, which were bound more strongly. This led to a higher catalytic activity and stability.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

氨功能化陶瓷膜支撑体担载钯纳米颗粒及其增强的催化性能

通讯作者: 陈日志, 邢卫红; 陈日志, 邢卫红

English

Catalytic activity of palladium nanoparticles immobilized on an amino-functionalized ceramic membrane support

Corresponding author: 陈日志, 邢卫红; 陈日志, 邢卫红

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

氨功能化陶瓷膜支撑体担载钯纳米颗粒及其增强的催化性能

通讯作者: 陈日志, 邢卫红; 陈日志, 邢卫红

English

Catalytic activity of palladium nanoparticles immobilized on an amino-functionalized ceramic membrane support

Corresponding author: 陈日志, 邢卫红; 陈日志, 邢卫红

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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