表面活性剂辅助共沉淀法制备Ni-Mg-Al固体碱催化剂用于CH<sub>4</sub>-CO<sub>2</sub>重整反应

引用本文: 谭鹏甲, 高志华, 沈朝峰, 杜亚丽, 李晓东, 黄伟. 表面活性剂辅助共沉淀法制备Ni-Mg-Al固体碱催化剂用于CH₄-CO₂重整反应[J]. 催化学报, 2014, 35(12): 1955-1971. doi: 10.1016/S1872-2067(14)60171-6 shu

Citation: Pengjia Tan, Zhihua Gao, Chaofeng Shen, Yali Du, Xiaodong Li, Wei Huang. Ni-Mg-Al solid basic layered double oxide catalysts prepared using surfactant-assisted coprecipitation method for CO₂ reforming of CH₄[J]. Chinese Journal of Catalysis, 2014, 35(12): 1955-1971. doi: 10.1016/S1872-2067(14)60171-6 shu

表面活性剂辅助共沉淀法制备Ni-Mg-Al固体碱催化剂用于CH₄-CO₂重整反应

谭鹏甲 ^a,b, ,
高志华 ^{a,
,} ,
沈朝峰 ^c, ,
杜亚丽 ^a, ,
李晓东 ^a, ,
黄伟 ^{a,
,}

通讯作者: 黄伟, 高志华; 黄伟, 高志华

基金项目:
国家高技术研究发展计划(863计划, 2013AA051201). (863计划, 2013AA051201)

摘要: 采用表面活性剂辅助共沉淀法制备了Ni-Mg-Al固体碱催化剂并用于CH₄-CO₂重整反应, 探讨了表面活性剂对Ni(111), Ni(200)晶面的择优取向作用, 在800 ℃下比较了不同表面活性剂制备的催化剂的催化性能, 详细考察了CTAB制备的催化剂CB-LDO在不同反应温度下的催化活性和稳定性.采用红外光谱、X射线衍射、程序升温还原、X射线光电子能谱、高分辨透射电镜和程序升温氧化等表征手段分析了催化剂的活性、稳定性和失活原因.结果表明, 四丙基氢氧化铵(TPAOH)促进Ni(200)的生长, 而聚氧乙烯-聚氧丙烯-聚氧乙烯(P123)、聚乙烯吡咯烷酮(PVP)和十六烷基三甲基溴化铵(CTAB)抑制Ni(200)晶面的生长;Ni(200)的结晶程度对CH₄的活化起到关键的作用, 催化剂CB-LDO在高温下反应会发生晶型的转化, Ni(200)晶面由于反应过程中生成NiAl₂O₄尖晶石而得到缓慢释放, 使催化剂的活性得以维持较高的水平.

关键词:

English

Ni-Mg-Al solid basic layered double oxide catalysts prepared using surfactant-assisted coprecipitation method for CO₂ reforming of CH₄

Pengjia Tan ^a,b, ,
Zhihua Gao ^{a,
,} ,
Chaofeng Shen ^c, ,
Yali Du ^a, ,
Xiaodong Li ^a, ,
Wei Huang ^{a,
,}

1.
a. Key Laboratory of Coal Science and Technology, Ministry of Education of China and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China;

Corresponding author: 黄伟, 高志华; 黄伟, 高志华

Received Date: 27 April 2014
Fund Project:
国家高技术研究发展计划(863计划, 2013AA051201).

Abstract: Ni-Mg-Al solid basic catalysts for CO₂ reforming of CH₄ were prepared using a surfactant-assisted coprecipitation method. The preferred orientations of the surfactants on the Ni(111) and Ni(200) crystal planes were investigated. The catalytic performance of the surfactant-modified catalysts was tested at 800 ℃. The cetyltrimethylammonium bromide (CTAB)-modified catalyst (CB-LDO; LDO = layered double oxide) was further studied at various reaction temperatures. All the catalysts were characterized using Fourier-transform infrared spectroscopy, X-ray diffraction, temperature- programmed reduction, X-ray photoelectron spectroscopy, high-resolution transmission electron microscopy, and temperature-programmed oxidation. The results show that growth of the Ni(200) plane is promoted by tetrapropylammonium hydroxide and restrained by P123, PVP, and CTAB. The crystallinity degree of Ni(200) plays a key role in the activation of CH₄. The CB-LDO catalysts retain high activities and stabilities, because of the crystal phase transformation at high temperature during the reaction; this leads to the formation of spinel NiAl₂O₄ and exposure of the Ni(200) crystal plane.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

表面活性剂辅助共沉淀法制备Ni-Mg-Al固体碱催化剂用于CH₄-CO₂重整反应

通讯作者: 黄伟, 高志华; 黄伟, 高志华

English

Ni-Mg-Al solid basic layered double oxide catalysts prepared using surfactant-assisted coprecipitation method for CO₂ reforming of CH₄

Corresponding author: 黄伟, 高志华; 黄伟, 高志华

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通讯作者: 陈斌, bchen63@163.com

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表面活性剂辅助共沉淀法制备Ni-Mg-Al固体碱催化剂用于CH4-CO2重整反应

通讯作者: 黄伟, 高志华; 黄伟, 高志华

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Ni-Mg-Al solid basic layered double oxide catalysts prepared using surfactant-assisted coprecipitation method for CO2 reforming of CH4

Corresponding author: 黄伟, 高志华; 黄伟, 高志华

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

表面活性剂辅助共沉淀法制备Ni-Mg-Al固体碱催化剂用于CH₄-CO₂重整反应

Ni-Mg-Al solid basic layered double oxide catalysts prepared using surfactant-assisted coprecipitation method for CO₂ reforming of CH₄

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