Morphology and Thermoresponsive Behavior of Hybrid Micelles of Polystyrene-b-Poly((N-isopropyl acrylamide)-co-(4-vinylbenzyl chloride)) with Prussian Blue

Citation: Xi-xian Ke, Jun-ting Xu, Bin-yang Du, Zhi-qiang Fan. Morphology and Thermoresponsive Behavior of Hybrid Micelles of Polystyrene-b-Poly((N-isopropyl acrylamide)-co-(4-vinylbenzyl chloride)) with Prussian Blue[J]. Chinese Journal of Polymer Science, 2015, 33(7): 1038-1047. doi: 10.1007/s10118-015-1656-5 shu

Morphology and Thermoresponsive Behavior of Hybrid Micelles of Polystyrene-b-Poly((N-isopropyl acrylamide)-co-(4-vinylbenzyl chloride)) with Prussian Blue

基金项目:
This work was financially supported by the National Natural Science Foundation of China (No. 21274130).

摘要: The hybrid micelles of polystyrene-b-poly((N-isopropyl acrylamide)-co-(4-vinylbenzyl chloride)) block copolymer (PS-b-P(NIPAM-co-VBC)) with Prussian blue (PB) in the corona were prepared by reaction of pentacyano(4-(dimethylamino)-pyridine)ferrate (Fe-DMAP)-attached PS-b-P(NIPAM-co-VBC) with FeCl3. The formation of the PB framework inside the micelles was verified by UV-Vis, FTIR and TGA. The morphology of the hybrid micelles was studied by TEM and compared with that of the neat and Fe-DMAP-attached PS-b-P(NIPAM-co-VBC). It is found that attachment of Fe-DMAP may change the short rod-like micelles of the neat PS-b-P(NIPAM-co-VBC) into spherical ones and lead to a smaller micelle size. The morphology of the hybrid micelles may be altered or remain unchanged after formation of the PB framework, depending on the chain structure of PS-b-P(NIPAM-co-VBC) and starting concentration. The thermoresponsive behavior of different micelles was studied using DLS. It is observed that attachment of Fe-DMAP can improve the hydrophilicity of the P(NIPAM-co-VBC) block, leading to weaker hysteresis of the micelle size during the heating and cooling cycle. However, the crosslinked PB framework in the micellar corona may result in a more evident hysteresis phenomenon and blur the two-stepwise change of the micellar size with temperature.

关键词:

English

Morphology and Thermoresponsive Behavior of Hybrid Micelles of Polystyrene-b-Poly((N-isopropyl acrylamide)-co-(4-vinylbenzyl chloride)) with Prussian Blue

Received Date: 06 November 2014
Revised Date: 27 November 2014
Available Online: 05 July 2015
Fund Project:
This work was financially supported by the National Natural Science Foundation of China (No. 21274130).

Abstract: The hybrid micelles of polystyrene-b-poly((N-isopropyl acrylamide)-co-(4-vinylbenzyl chloride)) block copolymer (PS-b-P(NIPAM-co-VBC)) with Prussian blue (PB) in the corona were prepared by reaction of pentacyano(4-(dimethylamino)-pyridine)ferrate (Fe-DMAP)-attached PS-b-P(NIPAM-co-VBC) with FeCl3. The formation of the PB framework inside the micelles was verified by UV-Vis, FTIR and TGA. The morphology of the hybrid micelles was studied by TEM and compared with that of the neat and Fe-DMAP-attached PS-b-P(NIPAM-co-VBC). It is found that attachment of Fe-DMAP may change the short rod-like micelles of the neat PS-b-P(NIPAM-co-VBC) into spherical ones and lead to a smaller micelle size. The morphology of the hybrid micelles may be altered or remain unchanged after formation of the PB framework, depending on the chain structure of PS-b-P(NIPAM-co-VBC) and starting concentration. The thermoresponsive behavior of different micelles was studied using DLS. It is observed that attachment of Fe-DMAP can improve the hydrophilicity of the P(NIPAM-co-VBC) block, leading to weaker hysteresis of the micelle size during the heating and cooling cycle. However, the crosslinked PB framework in the micellar corona may result in a more evident hysteresis phenomenon and blur the two-stepwise change of the micellar size with temperature.

Key words:

1. [1]
  Hamley, I.W., Angew. Chem. Int. Ed., 2003, 42: 1692
2. [2]
  He, W.N. and Xu, J.T., Prog. Polym. Sci., 2012, 37: 1350
3. [3]
  He, W.N., Zhou, B., Xu, J.T., Du, B.Y. and Fan, Z.Q., Macromolecules, 2012, 45: 9768
4. [4]
  Yang, J.X., Liu, L. and Xu, J.T., Prog. Chem., 2014, 26: 2811
5. [5]
  Deng, J.N., Wang, W.B., Zheng, Z.H., Ding, X.B. and Peng, Y.X., Chinese J. Polym. Sci., 2014, 32(7): 817
6. [6]
  Liu, H.J., Dong, R.H. and Chen, Y., Chinese J. Polym. Sci., 2014, 32(7): 961
7. [7]
  Xing, Y.H., Lin, S.L., Lin, J.P. and He, X.H., Chinese J. Polym. Sci., 2013, 31(5): 833
8. [8]
  Yang, J.X., He, W.N., Xu, J.T., Du, B.Y. and Fan, Z.Q., Chinese J. Polym. Sci., 2014, 32(9): 1128
9. [9]
  Roy, X., Hui, J.K., Rabnawaz, M., Liu, G.J. and Maclachlan, M.J., Angew. Chem. Int. Ed., 2011, 50: 1597
10. [10]
  Paz, F.A.A., Klinowski, J., Vilela, S.M.F., Tome, J.P.C., Cavaleiro, J.A.S. and Rocha, J., Chem. Soc. Rev., 2012, 41: 1088
11. [11]
  Bao, S.P., Ni, H., Wu, Q.H., Gao, H.Y., Liang, G.D., Zhu, F.M. and Wu, Q., Polymer, 2014, 55: 2205
12. [12]
  Liang, G.D., Ni, H., Bao, S.P., Zhu, F.M., Gao, H.Y., Wu, Q. and Tang, B.Z., Langmuir, 2014, 30: 6294
13. [13]
  Buser, H.J., Schwarzenbach, D., Petter, W. and Ludi, A., Inorg. Chem., 1977, 16: 2704
14. [14]
  Dunbar, K.R. and Heintz, R.A., Prog. Inorg. Chem., 1997, 45: 283
15. [15]
  Shores, M.P., Beauvais, L.G. and Long, J.R., J. Am. Chem. Soc., 1999, 121: 775
16. [16]
  Liang, G.D., Wu, Q.H., Qin, W.P., Bao, S.P., Zhu, F.M. and Wu, Q., Polym. Chem., 2013, 4: 3821
17. [17]
  Liang, G.D., Wu, Q.H., Bao, S.P., Zhu, F.M. and Wu, Q., Polym. Chem., 2013, 4: 5671
18. [18]
  Zhu, Y.L., Zhang, X.H., Guo, M.F., Huang, W.Q., Yang, J., Liang, Z.W. and Qiao, J.L., Chinese J. Polym. Sci., 2013, 31(8): 1061
19. [19]
  Vaucher, S., Fielden, J., Li, M., Dujardin, E. and Mann, S., Nano Lett., 2002, 2: 225
20. [20]
  Jin, E., Lu, X.F., Cui, L.L., Chao, D.M. and Wang, C., Electrochim. Acta, 2010, 55: 7230
21. [21]
  Chu, Z.Y., Zhang, Y.N., Dong, X.L., Jin, W.Q., Xu, N.P. and Tieke, B., J. Mater. Chem., 2010, 20: 7815
22. [22]
  Abdel-Razik, H.H., Asghar, B.H. and Kenawy, E., Chinese J. Polym. Sci., 2013, 31(2): 242
23. [23]
  Liang, G.D., Xu, J.T. and Wang, X.S., J. Am. Chem. Soc., 2009, 131: 5378
24. [24]
  Mchale, R., Liu, Y.B., Ghasdian, N., Hondow, N.S., Ye, S.J., Lu, Y., Brydson, R. and Wang, X.S., Nanoscale, 2011, 3: 3685
25. [25]
  Liu, Y.B. and Wang, X.S., Polym. Chem., 2012, 3: 2632
26. [26]
  Roy, X., Hui, J.K., Rabnawaz, M., Liu, G.J. and Maclachlan, M.J., J. Am. Chem. Soc., 2011, 133: 8420
27. [27]
  Cao, K., Xu, J.T. and Wang, X.S., Chinese J. Polym. Sci., 2012, 30(5): 674
28. [28]
  Uemura, T., Ohba, M. and Kitagawa, S., Inorg. Chem., 2004, 43: 7339
29. [29]
  Zhan, S.Z., Guo, D., Zhang, X.Y., Du, C.X., Zhu, Y. and Yang, R.N., Inorg. Chim. Acta, 2000, 298: 57
30. [30]
  Trent, J.S., Scheinbeim, J.I. and Couchman, P.R., Macromolecules, 1983, 16: 589
31. [31]
  Huong, D.M., Drechsler, M., Cantow, H.J. and Moller, M., Macromolecules, 1993, 26: 864
32. [32]
  Schild, H.G., Prog. Polym. Sci., 1992, 17: 163
33. [33]
  Du, B.Y., Mei, A.X., Yang, Y., Zhang, Q.F., Wang, Q., Xu, J.T. and Fan, Z.Q., Polymer, 2010, 51: 3493
34. [34]
  Ke, X.X., Wang, L., Xu, J.T., Du, B.Y., Tu, Y.F. and Fan, Z.Q., Soft Matter, 2014, 10: 5201
35. [35]
  Contreras-Caceres, R., Pacifico, J., Pastoriza-Santos, I., Perez-Juste, J., Fernandez-Barbero, A. and Liz-Marzan, L.M., Adv. Funct. Mater., 2009, 19: 3070
36. [36]
  Zhang, F., Hou, G.H., Dai, S.J., Lu, R. and Wang, C.C., Colloid. Polym. Sci., 2012, 290: 1341
37. [37]
  Liu, X.Y., Yang, J.M., Zha, L.S. and Jiang, Z.J., Chinese J. Polym. Sci., 2014, 32(11): 1544
38. [38]
  Liu, G.M., Cheng, H., Yan, L.F. and Zhang, G.Z., J. Phys. Chem. B, 2005, 109: 22603
39. [39]
  Wu, C. and Wang, X.H., Phys. Rev. Lett., 1998, 80: 4092
40. [40]
  Cao, Z., Du, B.Y., Chen, T.Y., Li, H.T., Xu, J.T. and Fan, Z.Q., Langmuir, 2008, 24: 5543
41. [41]
  Cheng, H., Shen, L. and Wu, C., Macromolecules, 2006, 39: 2325
42. [42]
  Plunkett, M.A., Wang, Z.H., Rutland, M.W. and Johannsmann, D., Langmuir, 2003, 19: 6837
43. [43]
  Ding, Y.W., Ye, X.D. and Zhang, G.Z., Macromolecules, 2005, 38: 904

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 809
HTML全文浏览量: 48

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Morphology and Thermoresponsive Behavior of Hybrid Micelles of Polystyrene-b-Poly((N-isopropyl acrylamide)-co-(4-vinylbenzyl chloride)) with Prussian Blue

English

Morphology and Thermoresponsive Behavior of Hybrid Micelles of Polystyrene-b-Poly((N-isopropyl acrylamide)-co-(4-vinylbenzyl chloride)) with Prussian Blue

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Morphology and Thermoresponsive Behavior of Hybrid Micelles of Polystyrene-b-Poly((N-isopropyl acrylamide)-co-(4-vinylbenzyl chloride)) with Prussian Blue

English

Morphology and Thermoresponsive Behavior of Hybrid Micelles of Polystyrene-b-Poly((N-isopropyl acrylamide)-co-(4-vinylbenzyl chloride)) with Prussian Blue

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs