Polypeptide Brushes Grown via Surface-initiated Ring-opening Polymerization of -Amino Acid N-Carboxyanhydrides

Citation: Yong Shen, Zhibo Li, Harm-Anton Klok. Polypeptide Brushes Grown via Surface-initiated Ring-opening Polymerization of -Amino Acid N-Carboxyanhydrides[J]. Chinese Journal of Polymer Science, 2015, 33(7): 931-946. doi: 10.1007/s10118-015-1654-7 shu

Polypeptide Brushes Grown via Surface-initiated Ring-opening Polymerization of -Amino Acid N-Carboxyanhydrides

1.
Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
2.
1. School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
3.
2. Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
4.
5.
É
基金项目:
This work was financially supported by the Sino-Swiss Science and Technology Cooperation (No. EG41-092011) as well as the Chinese Academy of Sciences (Visiting Professorship for Senior International Scientists to H.A.K.).

摘要: Polypeptide brushes are attractive platforms to generate functional and responsive interfaces that are of potential interest due to their possible biodegradability, biocompatibility and tunable secondary structures. Surface-initiated ring-opening polymerization (SI-ROP) of -amino acid N-carboxyanhydrides represents a powerful and versatile strategy to generate polypeptide brushes. This review is an attempt to capture the state-of-the-art in this field and highlights the latest developments in several selected areas. In addition to presenting an overview of the synthetic methods that have been used to generate polypeptide brushes via SI-ROP, this article will discuss the preparation of patterned polypeptide brushes, the conformational properties of surface-tethered polypeptides, ways to control chain orientation at surfaces as well as properties and applications of these thin polymer films.

关键词:

English

Polypeptide Brushes Grown via Surface-initiated Ring-opening Polymerization of -Amino Acid N-Carboxyanhydrides

1.
Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
2.
1. School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
3.
2. Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
4.
5.
É
Received Date: 16 March 2015
Revised Date: 22 March 2015
Available Online: 05 July 2015
Fund Project:
This work was financially supported by the Sino-Swiss Science and Technology Cooperation (No. EG41-092011) as well as the Chinese Academy of Sciences (Visiting Professorship for Senior International Scientists to H.A.K.).

Abstract: Polypeptide brushes are attractive platforms to generate functional and responsive interfaces that are of potential interest due to their possible biodegradability, biocompatibility and tunable secondary structures. Surface-initiated ring-opening polymerization (SI-ROP) of -amino acid N-carboxyanhydrides represents a powerful and versatile strategy to generate polypeptide brushes. This review is an attempt to capture the state-of-the-art in this field and highlights the latest developments in several selected areas. In addition to presenting an overview of the synthetic methods that have been used to generate polypeptide brushes via SI-ROP, this article will discuss the preparation of patterned polypeptide brushes, the conformational properties of surface-tethered polypeptides, ways to control chain orientation at surfaces as well as properties and applications of these thin polymer films.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

Polypeptide Brushes Grown via Surface-initiated Ring-opening Polymerization of -Amino Acid N-Carboxyanhydrides

English

Polypeptide Brushes Grown via Surface-initiated Ring-opening Polymerization of -Amino Acid N-Carboxyanhydrides

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中国化学会秘书处

Polypeptide Brushes Grown via Surface-initiated Ring-opening Polymerization of -Amino Acid N-Carboxyanhydrides

English

Polypeptide Brushes Grown via Surface-initiated Ring-opening Polymerization of -Amino Acid N-Carboxyanhydrides

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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