Effect of Molecular Weight on the Properties of Poly(butylene succinate)

Tian-xiang Jin Mi Zhou Shao-dong Hu Feng Chen Qiang Fu Yi Fu

Citation:  Tian-xiang Jin, Mi Zhou, Shao-dong Hu, Feng Chen, Qiang Fu, Yi Fu. Effect of Molecular Weight on the Properties of Poly(butylene succinate)[J]. Chinese Journal of Polymer Science, 2014, 32(7): 953-960. doi: 10.1007/s10118-014-1463-4 shu

Effect of Molecular Weight on the Properties of Poly(butylene succinate)

    通讯作者: Qiang Fu,
  • 基金项目:

    This work was financially supported by the National Natural Science Foundation of China (No. 51173112).

摘要: Poly(butylene succinate) (PBS) with different molecular weight was synthesized from 1, 4-butanediol and succinic acid by direct melt condensation. The synthesized PBS was identified by 1H-NMR and FTIR spectrometry. The molecular weight was calculated from the intrinsic viscosity, and its value was between 20000 and 70000. The crystallization behavior and crystal morphology as function of molecular weight were investigated by DSC and PLM, respectively. The mechanical properties and hydrolytic degradation behaviors related with change of molecular weight were also studied in this work. The results demonstrated that the properties of PBS were determined by both molecular weight and crystallization properties (crystallinity as well as crystal morphology). Our work is important for the design and preparation of PBS with proper molecular weight for its practical application.

English


    1. [1]

      Chrissafis, K., Paraskevopoulos, K.M. and Bikiaris, D.N., Thermochim. Acta, 2006, 440: 166

    2. [2]

      Zeng, J.B., Li, Y.D., Zhu, Q.Y., Yang, K.K., Wang, X.L. and Wang, Y.Z., Polymer, 2009, 50: 1178

    3. [3]

      Xu, J. and Guo, B.H. Microbial Succinic Acid, Its Polymer Poly(butylene succinate), and Applications, Springer press, Heidelberg, 2010, p. 347

    4. [4]

      Wang, T.C., Li, H.H. andYan, S.K., Chinese J. Polym. Sci., 2012, 30(2): 269

    5. [5]

      Zhan, M.Q., Chen, G.Y., Wei, Z.Y., Shi, Y.M. and Zhang, W.X., Chinese J. Polym. Sci., 2013, 31(1): 187

    6. [6]

      Han, Y.K., Kim, S.R. and Kim J., Macromol. Res., 2002, 10: 108

    7. [7]

      Ishihara, K., Ohara, S. and Yamamoto, H., Science, 2000, 290: 1140

    8. [8]

      Ishii, M., Okazaki, M., Shibasaki, Y., Ueda, M. and Teranishi, T., Biomacromolecules, 2001, 2: 1267

    9. [9]

      Xu, Y., Xu, J., Liu, D., Guo, B. and Xie, X., J. Appl. Polym. Sci., 2008, 109: 1881

    10. [10]

      Ihn, K.J., Yoo, E.S. and Im, S.S., Macromolecules, 1995, 28: 2460

    11. [11]

      Nunes, R.W., Martin, J.R. and Johnson, J.F., Polym. Eng. Sci., 1982, 22: 205

    12. [12]

      Song, D.K. and Sung, Y.K., J. Appl. Polym. Sci., 1995, 56: 1381

    13. [13]

      Yasuniwa, M. and Satou, T., J. Polym. Sci. B: Polym. Phys., 2002, 40: 2411

    14. [14]

      Yoo, E.S. and Im, S.S., J. Polym. Sci. B: Polym. Phys., 1999, 37: 1357

    15. [15]

      Miyata, T. and Masuko, T., Polymer, 1998, 39: 1399

    16. [16]

      Solomon, O.F. and Ciutǎ, I.Z., J. Appl. Polym. Sci., 1962, 6: 683

    17. [17]

      Papageorgiou, G.Z. and Bikiaris, D.N., J. Polym. Sci. B: Polym. Phys., 2006, 44: 584

    18. [18]

      Zen, A., Saphiannikova, M., Neher, D., Grenzer, J., Grigorian, S., Pietsch, U., Asawapirom, U., Janietz, S., Scherf, U., Lieberwirth, I. and Wegner, G., Macromolecules, 2006, 39: 2162

    19. [19]

      Cheng, S.Z.D., Chen, J., Zhang, A. and Heberer, D.P., J. Polym. Sci. B: Polym. Phys., 1991, 29: 299

    20. [20]

      Cheng, S.Z.D., Wu, S.S., Chen, J., Zhuo, Q., Quirk, R.P., von Meerwall E.D., Hsiao, B.S., Habenschuss, A. and Zschack, P.R., Macromolecules, 1993, 26: 5105

    21. [21]

      Lee, S.W., Chen, E., Zhang, A., Yoon, Y., Moon, B.S., Lee, S., Harris, F. W., Cheng, S.Z.D., von Meerwall, E.D., Hsiao, B.S., Verma, R. and Lando, J.B., Macromolecules, 1996, 29: 8816

    22. [22]

      Cheng, T.L. and Su, A.C., Polymer, 1995, 36: 73

    23. [23]

      Li, S.M., Garreau, H. and Vert, M., J. Mater. Sci-mater. M., 1990, 1: 123

  • 加载中
计量
  • PDF下载量:  0
  • 文章访问数:  862
  • HTML全文浏览量:  46
文章相关
  • 发布日期:  2014-07-05
  • 收稿日期:  2013-11-24
  • 修回日期:  2014-01-28
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章