Thienopyrazine or Dithiadiazatrindene Containing Low Band Gap Conjugated Polymers for Polymer Solar Cells

Mukhamed L. Keshtov Dmitry V. Marochkin Ying-ying Fu Zhi-yuan Xie Yan-hou Geng Vitaly S. Kochurov Alexei R. Khokhlov

Citation:  Mukhamed L. Keshtov, Dmitry V. Marochkin, Ying-ying Fu, Zhi-yuan Xie, Yan-hou Geng, Vitaly S. Kochurov, Alexei R. Khokhlov. Thienopyrazine or Dithiadiazatrindene Containing Low Band Gap Conjugated Polymers for Polymer Solar Cells[J]. Chinese Journal of Polymer Science, 2014, 32(7): 844-853. doi: 10.1007/s10118-014-1458-1 shu

Thienopyrazine or Dithiadiazatrindene Containing Low Band Gap Conjugated Polymers for Polymer Solar Cells

  • 基金项目:

    This work was financially supported by the Russian Foundation for Basic Research (GFEN_a No. 12-03-91175) and the National Natural Science Foundation of China (No. 51211120187).

摘要: Four new low-band-gap alternating copolymers (P-1, P-2, P-3 and P-4) based on electron-rich benzodithiophene and newly developed electron-deficient units, thienopyrazine or dithiadiazatrindene derivatives, were synthesized by Stille polycondensation. All polymers exhibit good solubility in common organic solvents and a broad absorption band in the visible to near-infrared regions. The film optical band gaps of the polymers are in the range of 1.28-2.07 eV and the highest occupied molecular orbital (HOMO) energy levels are in the range of -4.99 eV to -5.28 eV. Bulk heterojunction polymer solar cells (PSCs) of the polymers were fabricated with phenyl-C61-butyric acid methyl ester (PC61BM) as acceptor material, and a power conversion efficiency of 0.80% was realized with P-1 as donor material.

English


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  • 发布日期:  2014-07-05
  • 收稿日期:  2013-09-29
  • 修回日期:  2013-12-24
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