SIMULATION STUDY OF CO-ASSEMBLY OF ABC TRIBLOCK COPOLYMER/NANOPARTICLE INTO MULTICOMPARTMENT HYBRIDS IN SELECTIVE SOLVENT

Jie Cui Wei Li Wei Jiang

Citation:  Jie Cui, Wei Li, Wei Jiang. SIMULATION STUDY OF CO-ASSEMBLY OF ABC TRIBLOCK COPOLYMER/NANOPARTICLE INTO MULTICOMPARTMENT HYBRIDS IN SELECTIVE SOLVENT[J]. Chinese Journal of Polymer Science, 2013, 31(9): 1225-1232. doi: 10.1007/s10118-013-1323-7 shu

SIMULATION STUDY OF CO-ASSEMBLY OF ABC TRIBLOCK COPOLYMER/NANOPARTICLE INTO MULTICOMPARTMENT HYBRIDS IN SELECTIVE SOLVENT

    通讯作者: Wei Jiang,
  • 基金项目:

    This work was financially supported by the National Natural Science Foundation of China for General Program (No. 21274145).

摘要: Co-assembly of ABC linear triblock copolymer/nanoparticle into bump-surface multicompartment hybrids in selective solvent was studied through self-consistent field theory (SCFT) simulation. Results from three-dimensional SCFT simulation showed that the hybrid morphology depended on the length and number of grafted chains, whereas the number and shape of bumps relied on nanoparticle size. Moreover, the simulation results showed that the length and number of grafted chains had equivalent effect on hybrid morphology. Calculated results indicated that entropy was a more important factor than enthalpy in the co-assembly.

English


    1. [1]

      Ding, J.F. and Liu, G[J].J., Macromolecules.1997, 30:655-[2]Discher, B.M., Won, Y.Y., Ege, D.S., Lee, J.C.M., Bates, F.S., Discher, D.E. and Hammer, D.A., Science, 1999, 284: 1143[3]Kramer, E., Forster, S., Goltner, C. and Antonietti, M., Langmuir, 1998, 14: 2027[4]Zhu, J.T., Liao, Y[J].G. and Jiang, W., Langmuir.2004, 20:3809-[5]Massey, J., Power, K[J].N., Manners, I. and Winnik, M.A., J. Am. Chem. Soc.1998, 120:9533-[6]Vriezema, D.M., Hoogboom, J., Velonia, K., Takazawa, K., Christianen, P.C.M., Maan, J.C., Rowan, A.E. and Nolte, R.J.M., Angew. Chem., Int. Ed., 2003, 42: 772[7]Chan, Y.N., Lu, X.L., Chen, E.Q. and Mi, Y.L., Polymer, 2004, 45: 3465[8]Jenekhe, S.A. and Chen, X.L., Science, 1998, 279: 1903[9]Thurn-Albrecht, T., Schotter, J., Kastle, G.A., Emley, N., Shibauchi, T., Krusin-Elbaum, L., Guarini, K., Black, C.T., Tuominen, M.T. and Russell, T.P., Science, 2000, 290: 2126[10]Savic, R., Luo, L.B., Eisenberg, A. and Maysinger, D., Science, 2003, 300: 615[11]Allen, C., Maysinger, D[J].and Eisenberg, A., Colloids Surf. B.1999, 16:3-[12]Zhang, L.F. and Eisenberg, A[J]., Science.1995, 268:1728-[13]Nie, Z.H., Petukhova, A[J].and Kumacheva, E., Nat. Nanotechnol.2010, 5:15-[14]Glotzer, S.C. and Solomon, M[J].J., Nat. Mater.2007, 6:557-[15]Zhao, N., Vickery, J., Guerin, G., Park, J.I., Winnik, M.A. and Kumacheva, E., Angew. Chem., 2011, 123: 4702[16]Warren, S.C., Disalvo, F[J].J. and Wiesner, U., Nat. Mater.2007, 6:156-[17]Li, W.K., Liu, S.Q., Deng, R.H. and Zhu, J.T., Angew. Chem., 2011, 123: 5987[18]Bae, J., Lawrence, J., Miesch, C., Ribbe, A., Li, W.K., Emrick, T., Zhu, J.T. and Hayward, R.C., Adv. Mater., 2012, 24: 2735[19]He, J., Liu, Y.J., Babu, T., Wei, Z.J. and Nie, Z.H., J. Am. Chem. Soc., 2012, 134: 11342[20]Hu, J.M., Wu, T[J]., Zhang, G.Y. and Liu, S.Y., J. Am. Chem. Soc.2012, 134:7624-[21]Song, J.B., Cheng, L., Liu, A.P., Yin, J., Kuang, M. and Duan, H.W., J. Am. Chem. Soc., 2011, 133: 10760[22]Li, Z.B., Kesselman, E., Talmon, Y., Hillmyer, M.A. and Lodge, T.P., Science, 2004, 306: 98[23]Li, Z.B., Hillmyer, M.A. and Lodge, T.P., Langmuir, 2006, 22: 9409[24]Saito, N., Liu, C., Lodge, T.P. and Hillmyer, M.A., Macromolecules, 2008, 41: 8815[25]Moughton, A.O., Hillmyer, M[J].A. and Lodge, T.P., Macromolecules.2012, 45:2-[26]Mackay, M.E., Tuteja, A., Duxbury, P.M., Hawker, C.J., Van Horn, B., Guan, Z.B., Chen, G.H. and Krishnan, R.S., Science, 2006, 311: 1740[27]Thompson, R.B., Ginzburg, V.V., Matsen, M.W. and Balazs, A.C., Science, 2001, 292: 2469[28]Hooper, J.B. and Schweizer, K[J].S., Macromolecules.2006, 39:5133-[29]Drolet, F. and Fredrickson, G[J].H., Phys. Rev. Lett.1999, 83:4317-[30]Drolet, F. and Fredrickson, G[J].H., Macromolecules.2001, 34:5317-[31]Fredrickson, G.H., Ganesan, V[J].and Drolet, F., Macromolecules.2002, 35:16-[32]Ma, Z.W., Yu, H[J].Z. and Jiang, W., J. Phys. Chem. B.2009, 113:3333-

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  • 发布日期:  2013-09-05
  • 收稿日期:  2013-03-21
  • 修回日期:  2013-05-17
通讯作者: 陈斌, bchen63@163.com
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