Application of Et3NHCl-AlCl3 Ionic Liquid as an Initiator in Cationic Copolymerization of 1, 3-Pentadiene with Styrene

Yuan Yuan WANG Hui SUN Juan LI Dong JIANG Li Yi DAI

引用本文: Yuan Yuan WANG,  Hui SUN,  Juan LI,  Dong JIANG,  Li Yi DAI. Application of Et3NHCl-AlCl3 Ionic Liquid as an Initiator in Cationic Copolymerization of 1, 3-Pentadiene with Styrene[J]. Chinese Chemical Letters, 2006, 17(1): 117-120. shu
Citation:  Yuan Yuan WANG,  Hui SUN,  Juan LI,  Dong JIANG,  Li Yi DAI. Application of Et3NHCl-AlCl3 Ionic Liquid as an Initiator in Cationic Copolymerization of 1, 3-Pentadiene with Styrene[J]. Chinese Chemical Letters, 2006, 17(1): 117-120. shu

Application of Et3NHCl-AlCl3 Ionic Liquid as an Initiator in Cationic Copolymerization of 1, 3-Pentadiene with Styrene

  • 基金项目:

    This work was financially supported by the Ministry of Education of China (No. 105075).

摘要: The random copolymer poly (1, 3-pentadiene-co-styrene) formed through cationic copolymerization using the triethylamine hydrochloride and hydrous aluminium chloride (Et3NHC1-A1C13) room temperature ionic liquid as initiating agent in toluene was analyzed using IR spectra in conjunction with gel permeation chromatography (GPC). The room temperature ionic liquid was found to have high initiatic activity for copolymerization.

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  • 收稿日期:  2005-04-04
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