Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)2(CH2=CH-CH2-SO3)·H2O

引用本文: Zhi LIU, Qi FANG, Wen Tao YU, Min Hua JIANG, De Qing ZHANG, Dao Ben ZHU. Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)₂(CH₂=CH-CH₂-SO₃)·H₂O[J]. Chinese Chemical Letters, 2003, 14(4): 433-436. shu

Citation: Zhi LIU, Qi FANG, Wen Tao YU, Min Hua JIANG, De Qing ZHANG, Dao Ben ZHU. Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)₂(CH₂=CH-CH₂-SO₃)·H₂O[J]. Chinese Chemical Letters, 2003, 14(4): 433-436. shu

Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)₂(CH₂=CH-CH₂-SO₃)·H₂O

1.
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100;
2.
Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080
基金项目:
This project was supported by a grant for the State Key Program of China and by the National Natural Science Foundation of China (No.20172034), and also supported by the open laboratory of organic solid of Institute of Chemistry of the Chinese Academy of Sciences.

摘要: Electro-oxidation of 3,4,3', 4(-bis(ethylenedithio)-2,2',5,5(-tetrathiafulvalen (abbr. ET) in the presence of allylsulfonate affords a new charge-transfer salt (ET)₂(CH₂=CH-CH₂-SO₃)·H₂O. The single crystal structure of the title compound is determined to be in orthorhombic crystal system, Pma2 space group. This salt is a semiconductor and its room-temperature conductivity is 0.0489Ω^-1·m^-1.

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English

Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)₂(CH₂=CH-CH₂-SO₃)·H₂O

1.
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100;
2.
Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080
Received Date: 27 May 2002
Fund Project:
This project was supported by a grant for the State Key Program of China and by the National Natural Science Foundation of China (No.20172034), and also supported by the open laboratory of organic solid of Institute of Chemistry of the Chinese Academy of Sciences.

Abstract: Electro-oxidation of 3,4,3', 4(-bis(ethylenedithio)-2,2',5,5(-tetrathiafulvalen (abbr. ET) in the presence of allylsulfonate affords a new charge-transfer salt (ET)₂(CH₂=CH-CH₂-SO₃)·H₂O. The single crystal structure of the title compound is determined to be in orthorhombic crystal system, Pma2 space group. This salt is a semiconductor and its room-temperature conductivity is 0.0489Ω^-1·m^-1.

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)₂(CH₂=CH-CH₂-SO₃)·H₂O

English

Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)₂(CH₂=CH-CH₂-SO₃)·H₂O

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