引用本文:
Yong Qiang MA, Xiao CHEN, Jing LI, Qing Lan XIE, Hong Gen WANG. Synthesis and Reaction of[MnRe(CO)6(μ-SH)(μ-SC(H)PPr3i)(PPh3)][J]. Chinese Chemical Letters,
2003, 14(4): 413-416.
Citation: Yong Qiang MA, Xiao CHEN, Jing LI, Qing Lan XIE, Hong Gen WANG. Synthesis and Reaction of[MnRe(CO)6(μ-SH)(μ-SC(H)PPr3i)(PPh3)][J]. Chinese Chemical Letters, 2003, 14(4): 413-416.
Citation: Yong Qiang MA, Xiao CHEN, Jing LI, Qing Lan XIE, Hong Gen WANG. Synthesis and Reaction of[MnRe(CO)6(μ-SH)(μ-SC(H)PPr3i)(PPh3)][J]. Chinese Chemical Letters, 2003, 14(4): 413-416.
Synthesis and Reaction of[MnRe(CO)6(μ-SH)(μ-SC(H)PPr3i)(PPh3)]
摘要:
The synthesis, the crystal structure and the reaction of the hetero-binuclear complex[MnRe(CO)6(μ-SH)(μ-SC(H)PPr3i)(PPh3)] are reported. The results of single crystal X-ray structure analysis showed that the fragments Mn(CO)3 and Re(CO)3 were bridged by SH and SC(H)PPr3i. The title complexes can react with BunLi and RX forming complexes MnRe(CO)6(μ-SR)(μ-SC(H)PPr3i)(PPh3) (R=Me, CH2CH=CH2, SnBu3n).
English
Synthesis and Reaction of[MnRe(CO)6(μ-SH)(μ-SC(H)PPr3i)(PPh3)]
Abstract:
The synthesis, the crystal structure and the reaction of the hetero-binuclear complex[MnRe(CO)6(μ-SH)(μ-SC(H)PPr3i)(PPh3)] are reported. The results of single crystal X-ray structure analysis showed that the fragments Mn(CO)3 and Re(CO)3 were bridged by SH and SC(H)PPr3i. The title complexes can react with BunLi and RX forming complexes MnRe(CO)6(μ-SR)(μ-SC(H)PPr3i)(PPh3) (R=Me, CH2CH=CH2, SnBu3n).
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Key words:
- Hetero-binuclear complexes
- / synthesis
- / reaction
- / crystal structure
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