引用本文:
Xing Guo CHEN, Chu Luo YANG, Jin Gui QIN, Kyuya YAKUSHI, Yasuhiro NAKAZAWA, Kenji ICHIMURA. A New Inorganic-organic Nanocomposite, 4,4'-Bipyridine Intercalated into Lamellar FePS3[J]. Chinese Chemical Letters,
2003, 14(11): 1179-1181.
Citation: Xing Guo CHEN, Chu Luo YANG, Jin Gui QIN, Kyuya YAKUSHI, Yasuhiro NAKAZAWA, Kenji ICHIMURA. A New Inorganic-organic Nanocomposite, 4,4'-Bipyridine Intercalated into Lamellar FePS3[J]. Chinese Chemical Letters, 2003, 14(11): 1179-1181.
Citation: Xing Guo CHEN, Chu Luo YANG, Jin Gui QIN, Kyuya YAKUSHI, Yasuhiro NAKAZAWA, Kenji ICHIMURA. A New Inorganic-organic Nanocomposite, 4,4'-Bipyridine Intercalated into Lamellar FePS3[J]. Chinese Chemical Letters, 2003, 14(11): 1179-1181.
A New Inorganic-organic Nanocomposite, 4,4'-Bipyridine Intercalated into Lamellar FePS3
摘要:
A new intercalation compound, Fe0.85PS3(4,4'-bipyH)0.30 (4,4'-bipy=4,4'-bipyridine), is obtained by the intercalation of 4,4'-bipyridine·2HCl with lamellar FePS3, which is characterized by elemental analysis, powder X-ray diffraction, infrared spectroscopy. By comparison with the pure FePS3, the lattice spacing of Fe0.85PS3(4,4'-bipyH)0.30 is expanded by~5.7(Å), indicating that the ring plane of the guest is perpendicular to the layer of the host. The magnetic property of Fe0.85PS3(4,4'-bipyH)0.30 is studied with SQUID. It exhibits an antiferromagnetic phase transition with TN of about 70 K.
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关键词:
- Intercalation
- / lamellar FePS3
- / magnetic property
English
A New Inorganic-organic Nanocomposite, 4,4'-Bipyridine Intercalated into Lamellar FePS3
Abstract:
A new intercalation compound, Fe0.85PS3(4,4'-bipyH)0.30 (4,4'-bipy=4,4'-bipyridine), is obtained by the intercalation of 4,4'-bipyridine·2HCl with lamellar FePS3, which is characterized by elemental analysis, powder X-ray diffraction, infrared spectroscopy. By comparison with the pure FePS3, the lattice spacing of Fe0.85PS3(4,4'-bipyH)0.30 is expanded by~5.7(Å), indicating that the ring plane of the guest is perpendicular to the layer of the host. The magnetic property of Fe0.85PS3(4,4'-bipyH)0.30 is studied with SQUID. It exhibits an antiferromagnetic phase transition with TN of about 70 K.
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Key words:
- Intercalation
- / lamellar FePS3
- / magnetic property
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