引用本文:
Sheng Lin LIU, Long Ya XU, Su Juan XIE, Qing Xia WANG. Partial Oxidation of Butane to Syngas over Nickel SupportedCatalysts Modified by Alkali Metal Oxide and Rare-Earth Metal Oxide[J]. Chinese Chemical Letters,
2001, 12(1): 43-46.
Citation: Sheng Lin LIU, Long Ya XU, Su Juan XIE, Qing Xia WANG. Partial Oxidation of Butane to Syngas over Nickel SupportedCatalysts Modified by Alkali Metal Oxide and Rare-Earth Metal Oxide[J]. Chinese Chemical Letters, 2001, 12(1): 43-46.

Citation: Sheng Lin LIU, Long Ya XU, Su Juan XIE, Qing Xia WANG. Partial Oxidation of Butane to Syngas over Nickel SupportedCatalysts Modified by Alkali Metal Oxide and Rare-Earth Metal Oxide[J]. Chinese Chemical Letters, 2001, 12(1): 43-46.

Partial Oxidation of Butane to Syngas over Nickel SupportedCatalysts Modified by Alkali Metal Oxide and Rare-Earth Metal Oxide
摘要:
The partial oxidation of butane (POB) to syngas over nickel supported catalysts was first investigated with a flow-reactor, TG and UVRRS. The NiO/γ-Al2O3 is the most suitable for the POB among NiO/γ-Al2O3, NiO/MgO and NiO/SiO2. And the reaction performance of the NiO/γ-Al2O3 shows little difference from those of the nickel supported catalysts modified by alkali metal oxide and rare-earth metal oxide. However, modification with Li2O and La2O3 can suppress carbon-deposition of the NiO/γ-Al2O3, which contains graphite-like species during the POB reaction.
English
Partial Oxidation of Butane to Syngas over Nickel SupportedCatalysts Modified by Alkali Metal Oxide and Rare-Earth Metal Oxide
Abstract:
The partial oxidation of butane (POB) to syngas over nickel supported catalysts was first investigated with a flow-reactor, TG and UVRRS. The NiO/γ-Al2O3 is the most suitable for the POB among NiO/γ-Al2O3, NiO/MgO and NiO/SiO2. And the reaction performance of the NiO/γ-Al2O3 shows little difference from those of the nickel supported catalysts modified by alkali metal oxide and rare-earth metal oxide. However, modification with Li2O and La2O3 can suppress carbon-deposition of the NiO/γ-Al2O3, which contains graphite-like species during the POB reaction.
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Key words:
- Partial oxidation of butane
- / syngas
- / carbon-deposition
- / nickel supported catalysts.

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