Partial Oxidation of Butane to Syngas over Nickel SupportedCatalysts Modified by Alkali Metal Oxide and Rare-Earth Metal Oxide

Sheng Lin LIU Long Ya XU Su Juan XIE Qing Xia WANG

引用本文: Sheng Lin LIU,  Long Ya XU,  Su Juan XIE,  Qing Xia WANG. Partial Oxidation of Butane to Syngas over Nickel SupportedCatalysts Modified by Alkali Metal Oxide and Rare-Earth Metal Oxide[J]. Chinese Chemical Letters, 2001, 12(1): 43-46. shu
Citation:  Sheng Lin LIU,  Long Ya XU,  Su Juan XIE,  Qing Xia WANG. Partial Oxidation of Butane to Syngas over Nickel SupportedCatalysts Modified by Alkali Metal Oxide and Rare-Earth Metal Oxide[J]. Chinese Chemical Letters, 2001, 12(1): 43-46. shu

Partial Oxidation of Butane to Syngas over Nickel SupportedCatalysts Modified by Alkali Metal Oxide and Rare-Earth Metal Oxide

摘要: The partial oxidation of butane (POB) to syngas over nickel supported catalysts was first investigated with a flow-reactor, TG and UVRRS. The NiO/γ-Al2O3 is the most suitable for the POB among NiO/γ-Al2O3, NiO/MgO and NiO/SiO2. And the reaction performance of the NiO/γ-Al2O3 shows little difference from those of the nickel supported catalysts modified by alkali metal oxide and rare-earth metal oxide. However, modification with Li2O and La2O3 can suppress carbon-deposition of the NiO/γ-Al2O3, which contains graphite-like species during the POB reaction.

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  • 发布日期:  2001-02-01
  • 收稿日期:  2000-06-15
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