引用本文:
Bao Shan WANG, Hua HOU, Yue Shu GU. Studies on the Kinetics of the FO+CO Reaction[J]. Chinese Chemical Letters,
1998, 9(9): 863-866.
Citation: Bao Shan WANG, Hua HOU, Yue Shu GU. Studies on the Kinetics of the FO+CO Reaction[J]. Chinese Chemical Letters, 1998, 9(9): 863-866.
Citation: Bao Shan WANG, Hua HOU, Yue Shu GU. Studies on the Kinetics of the FO+CO Reaction[J]. Chinese Chemical Letters, 1998, 9(9): 863-866.
Studies on the Kinetics of the FO+CO Reaction
摘要:
Two competitive channels of the reaction of FO with CO were calculated by the TST-RRKM theory and the classical transition state theory, respectively. The results show that the direct channel dominates the reaction over the entire studied temperature range and the addition-elimination channel has important contributions at low temperatures. The cited reaction does not influence the fluorine regeneration and the sink of CO in the stratosphere.
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关键词:
- ab initio
- / kinetic calculation
- / RRKM
English
Studies on the Kinetics of the FO+CO Reaction
Abstract:
Two competitive channels of the reaction of FO with CO were calculated by the TST-RRKM theory and the classical transition state theory, respectively. The results show that the direct channel dominates the reaction over the entire studied temperature range and the addition-elimination channel has important contributions at low temperatures. The cited reaction does not influence the fluorine regeneration and the sink of CO in the stratosphere.
-
Key words:
- ab initio
- / kinetic calculation
- / RRKM
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