引用本文:
Shuang Hui LUO, Hui Ming JMNG, You Cheng LIU, Qing Xiang GUO. A Study on the Driving Force for Binding of Benzene Derivatives by α-and β-Cyclodextrin[J]. Chinese Chemical Letters,
1998, 9(5): 463-464.
Citation: Shuang Hui LUO, Hui Ming JMNG, You Cheng LIU, Qing Xiang GUO. A Study on the Driving Force for Binding of Benzene Derivatives by α-and β-Cyclodextrin[J]. Chinese Chemical Letters, 1998, 9(5): 463-464.
Citation: Shuang Hui LUO, Hui Ming JMNG, You Cheng LIU, Qing Xiang GUO. A Study on the Driving Force for Binding of Benzene Derivatives by α-and β-Cyclodextrin[J]. Chinese Chemical Letters, 1998, 9(5): 463-464.
A Study on the Driving Force for Binding of Benzene Derivatives by α-and β-Cyclodextrin
摘要:
A three-dimensional diagram shows that the association constants (Ka) for the inclusion of a- and β-CD with substituted benzene are mainly correlated with the molar refraction (Rm) and hydrophobic constant (πx)of the substituents of guest compounds. It reveals that the inclusion of cyclodextrin with the substituted benzene is dominantly driven by van der Waals forces and hydrophobic interactions.
English
A Study on the Driving Force for Binding of Benzene Derivatives by α-and β-Cyclodextrin
Abstract:
A three-dimensional diagram shows that the association constants (Ka) for the inclusion of a- and β-CD with substituted benzene are mainly correlated with the molar refraction (Rm) and hydrophobic constant (πx)of the substituents of guest compounds. It reveals that the inclusion of cyclodextrin with the substituted benzene is dominantly driven by van der Waals forces and hydrophobic interactions.
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Key words:
- benzene derivatives
- / cyclodextrin
- / driving force
- / inclusion complexation
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