引用本文:
Yong Min ZHANG, Wen Ying HAO, You HUANG, Jia Jun ZHU. Samarium Diiodide-Mediated Reductive Cleavage of Se-Se Bond ofDiacyl Diselenides:A New Method for Synthesis of β-Selenoesters[J]. Chinese Chemical Letters,
1998, 9(5): 417-420.
Citation: Yong Min ZHANG, Wen Ying HAO, You HUANG, Jia Jun ZHU. Samarium Diiodide-Mediated Reductive Cleavage of Se-Se Bond ofDiacyl Diselenides:A New Method for Synthesis of β-Selenoesters[J]. Chinese Chemical Letters, 1998, 9(5): 417-420.
Citation: Yong Min ZHANG, Wen Ying HAO, You HUANG, Jia Jun ZHU. Samarium Diiodide-Mediated Reductive Cleavage of Se-Se Bond ofDiacyl Diselenides:A New Method for Synthesis of β-Selenoesters[J]. Chinese Chemical Letters, 1998, 9(5): 417-420.
Samarium Diiodide-Mediated Reductive Cleavage of Se-Se Bond ofDiacyl Diselenides:A New Method for Synthesis of β-Selenoesters
摘要:
The reduction of diacyl diselenides by samarium diiodide led to the production of samarium acylselenolates, which reacted with α,β-unsaturated esters or nitriles to give β-selenoesters or selenonitriles under mild and neutral conditions.
English
Samarium Diiodide-Mediated Reductive Cleavage of Se-Se Bond ofDiacyl Diselenides:A New Method for Synthesis of β-Selenoesters
Abstract:
The reduction of diacyl diselenides by samarium diiodide led to the production of samarium acylselenolates, which reacted with α,β-unsaturated esters or nitriles to give β-selenoesters or selenonitriles under mild and neutral conditions.
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Key words:
- reductive cleavage
- / samarium diiodide
- / diacyl diselenide
- / β-selenoester
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