Chiral Synthesis of the Intermediate of (-)-Gibberellin A12

Xiao-Jiang HAO Manabu NODE Kaoru FUJI

引用本文: Xiao-Jiang HAO,  Manabu NODE,  Kaoru FUJI. Chiral Synthesis of the Intermediate of (-)-Gibberellin A12[J]. Chinese Chemical Letters, 1997, 8(11): 951-952. shu
Citation:  Xiao-Jiang HAO,  Manabu NODE,  Kaoru FUJI. Chiral Synthesis of the Intermediate of (-)-Gibberellin A12[J]. Chinese Chemical Letters, 1997, 8(11): 951-952. shu

Chiral Synthesis of the Intermediate of (-)-Gibberellin A12

摘要: (-)-Dimethyl(1R,4aS)-1,4a-dimethyl-6-nitro-1,2,3,4,4a-pentahydrofluorene-1,9-dicarboxy-late (1) was synthesized from (R)-(+)-2-methyl-2-(2'-nitrovinyl)-δ-valerolactone (2),which constitutes a formal total synthesis of (-)-gibberellin A12.

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  • 收稿日期:  1997-09-04
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