引用本文:
Bei Sheng KANG, Ling Hong WENG, Liang Ren HUANG, Xue Tai CHEN, Han Qin LIU, Jia Xi LU. SYNTHESIS AND STRUCTURE OF A LINEAR TRIVANADIUM COMPOUND(PH4P)[V3(OC6H4S-o)6]-SIMULATION OF THE VANADIUM SITE OF ALTERNATIVE NITROGENASE[J]. Chinese Chemical Letters,
1990, 1(1): 79-80.
Citation: Bei Sheng KANG, Ling Hong WENG, Liang Ren HUANG, Xue Tai CHEN, Han Qin LIU, Jia Xi LU. SYNTHESIS AND STRUCTURE OF A LINEAR TRIVANADIUM COMPOUND(PH4P)[V3(OC6H4S-o)6]-SIMULATION OF THE VANADIUM SITE OF ALTERNATIVE NITROGENASE[J]. Chinese Chemical Letters, 1990, 1(1): 79-80.
Citation: Bei Sheng KANG, Ling Hong WENG, Liang Ren HUANG, Xue Tai CHEN, Han Qin LIU, Jia Xi LU. SYNTHESIS AND STRUCTURE OF A LINEAR TRIVANADIUM COMPOUND(PH4P)[V3(OC6H4S-o)6]-SIMULATION OF THE VANADIUM SITE OF ALTERNATIVE NITROGENASE[J]. Chinese Chemical Letters, 1990, 1(1): 79-80.
SYNTHESIS AND STRUCTURE OF A LINEAR TRIVANADIUM COMPOUND(PH4P)[V3(OC6H4S-o)6]-SIMULATION OF THE VANADIUM SITE OF ALTERNATIVE NITROGENASE
摘要:
Compound(PH4P)[V3MP6](MPH2=o-HOC6H4SH)was obtained by reaction of VCl3 and Na2MP in ethanol in the presence of PH4PBr.It is triclinic and crystallizes in space group P1, fw=1237.3, a=14.127(4), b=14.342(4), c=15.878(4)Å;α=65.08(2), β=73.09(2), γ=78.68(2)°;V=2781.3 Å3, Z=2, dc=1.48 g/cm3.Final R factor is 0.063.The three vanadium atoms are linearly arranged and bridged by the oxygen atoms and terminally chelated by the thiolato-atoms of the six MP2-ligands in pseudo-S6 symmetry.
English
SYNTHESIS AND STRUCTURE OF A LINEAR TRIVANADIUM COMPOUND(PH4P)[V3(OC6H4S-o)6]-SIMULATION OF THE VANADIUM SITE OF ALTERNATIVE NITROGENASE
Abstract:
Compound(PH4P)[V3MP6](MPH2=o-HOC6H4SH)was obtained by reaction of VCl3 and Na2MP in ethanol in the presence of PH4PBr.It is triclinic and crystallizes in space group P1, fw=1237.3, a=14.127(4), b=14.342(4), c=15.878(4)Å;α=65.08(2), β=73.09(2), γ=78.68(2)°;V=2781.3 Å3, Z=2, dc=1.48 g/cm3.Final R factor is 0.063.The three vanadium atoms are linearly arranged and bridged by the oxygen atoms and terminally chelated by the thiolato-atoms of the six MP2-ligands in pseudo-S6 symmetry.
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