引用本文:
Bin YE, Jin Li ZHANG, Ming Qing CHEN, Yu Lin WU. SYNTHESIS OF 1, 6-DIEPI-DIHYDROARTEANNUIC ACID[J]. Chinese Chemical Letters,
1990, 1(1): 65-68.
Citation: Bin YE, Jin Li ZHANG, Ming Qing CHEN, Yu Lin WU. SYNTHESIS OF 1, 6-DIEPI-DIHYDROARTEANNUIC ACID[J]. Chinese Chemical Letters, 1990, 1(1): 65-68.
Citation: Bin YE, Jin Li ZHANG, Ming Qing CHEN, Yu Lin WU. SYNTHESIS OF 1, 6-DIEPI-DIHYDROARTEANNUIC ACID[J]. Chinese Chemical Letters, 1990, 1(1): 65-68.
SYNTHESIS OF 1, 6-DIEPI-DIHYDROARTEANNUIC ACID
摘要:
R(+)-Citronellal was converted into a key intermediate, (unsaturated ketone 5)in three steps, which led to 6 having the frame of arteannuic acid through intramolecular ene reaction.Further modification of 6afforded 1, 6-epimer of dihydroarteannuic acid.The configuration of 7 was determined by X-ray diffraction analysis.
English
SYNTHESIS OF 1, 6-DIEPI-DIHYDROARTEANNUIC ACID
Abstract:
R(+)-Citronellal was converted into a key intermediate, (unsaturated ketone 5)in three steps, which led to 6 having the frame of arteannuic acid through intramolecular ene reaction.Further modification of 6afforded 1, 6-epimer of dihydroarteannuic acid.The configuration of 7 was determined by X-ray diffraction analysis.
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