引用本文:
喻远达, 谷淑湘, 罗小健, 马铭, 何鼎胜. N902-煤油-HCl反萃分散组合液膜迁移和分离铜[J]. 应用化学,
2006, 23(7): 766-769.
Citation: YU Yuan-Da, GU Shu-Xiang, LUO Xiao-Jian, MA Ming, HE Ding-Sheng. Transport and Separation of Cu(Ⅱ) by N902-Kerosene-HCl Strip dispersion Hybrid Liquid Membrane[J]. Chinese Journal of Applied Chemistry, 2006, 23(7): 766-769.

Citation: YU Yuan-Da, GU Shu-Xiang, LUO Xiao-Jian, MA Ming, HE Ding-Sheng. Transport and Separation of Cu(Ⅱ) by N902-Kerosene-HCl Strip dispersion Hybrid Liquid Membrane[J]. Chinese Journal of Applied Chemistry, 2006, 23(7): 766-769.

N902-煤油-HCl反萃分散组合液膜迁移和分离铜
摘要:
研究了十二醇浓度、料液pH、反萃液与有机相的体积比、料液和反萃分散相流量对含N902作载体的新型反萃分散液膜迁移和分离铜的影响。溶剂萃取实验证实,1 mol铜和2 mol载体反应,形成1 mol铜-载体配合物。膜迁移实验证明,当铜、铁浓度比和铜、锌浓度比接近1,料液pH=2,迁移4 h,反萃液中分别回收铜93.6%、铁1.83%和铜89.8%,锌1.38%。当料液pH=1.5,其中Cu2+、Fe3+、Co2+、Ni2+和Zn2+的质量浓度分别是4.52、5.07、0.442、35.7和1.24 g/L时,迁移6 h,反萃液中Cu2+一次回收高达81.5%,Fe3+、Co2+、Ni2+和Zn2+的回收均未超过2.10%。该反萃分散组合液膜能有效地迁移和富集铜,并有效地与料液中的锌、铁、钴、镍分离,N902是一种高效的铜萃取剂。反萃分散组合液膜具有改善膜稳定性、提高流量、富集和回收高浓度溶质的溶液,不使用高活性表面活性剂和破乳装置的优点。
English
Transport and Separation of Cu(Ⅱ) by N902-Kerosene-HCl Strip dispersion Hybrid Liquid Membrane
Abstract:
A novel liquid membrane system,denoted as strip dispersion hybrid liquid membrane(SDHLM),containing N902 in kerosene as carrier,was studied as the function of dodecanol concentration,pH in feed phase,volume ratio between stripping solution and organic phase,and circulating flux of feed phase or strip dispersion phase.Solvent extraction verified that 1 mol of Cu2+ ions reacted with 2 mol of carrier and formed 1 mol of the Cu(Ⅱ)-carrier complex.The experiments showed that Cu(Ⅱ) could be efficiently transported into the stripping solution by SDHLM.When pH=2 in the feed phase,the recovery of copper(Ⅱ) in the stripping phase was 93.6%,while iron(Ⅲ) was 1.83% for Cu2+/Fe3+=1.The recovery of copper(Ⅱ) in the stripping) phase was 89.8%,while zinc(Ⅱ) was 1.38% for Cu2+/Zn2+=1 after transport for 4 h.When the concentrations of Cu2+,Fe3+,Co2+,Ni2+ and Zn2+ in the feed phase(pH=1.5) were 4.52,5.07,0.442,35.7 and 1.24 g/L,respectively,the recovery of Cu2+ in the stripping phase was 81.5%,while other metal ions were below 2.10% after the transport for 6 h.Separation experiments indicated that N902 was an excellent extractant for Cu(Ⅱ).SDHLM has several advantages over SLM and ELM:increased membrane stability,improved flux,improved recovery of target species concentration,no usage of high active surfactant and demulsification) device,and reduced cost.
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Key words:
- strip dispersion hybrid liquid membrane
- / copper
- / N902
- / separation
- / transport
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