引用本文:
赵建社, 张荣兰, 顾爱萍, 郝葳潇, 何水样, 刘建宁. 甲基环戊二烯基水杨酸钛(Ⅳ)配合物的合成与表征[J]. 应用化学,
2002, 19(7): 667-671.
Citation: ZHAO Jian-She, ZHANG Rong-Lan, GU Ai-Ping, HAO Wei-Xiao, HE Shui-Yang, LIU Jian-Ning. Synthesis and Characterization of Dimethylcyclo-pentadienyl Salicylato- and Ring-substituted Salicylato-Titanium(Ⅳ) Complexes[J]. Chinese Journal of Applied Chemistry, 2002, 19(7): 667-671.
Citation: ZHAO Jian-She, ZHANG Rong-Lan, GU Ai-Ping, HAO Wei-Xiao, HE Shui-Yang, LIU Jian-Ning. Synthesis and Characterization of Dimethylcyclo-pentadienyl Salicylato- and Ring-substituted Salicylato-Titanium(Ⅳ) Complexes[J]. Chinese Journal of Applied Chemistry, 2002, 19(7): 667-671.
甲基环戊二烯基水杨酸钛(Ⅳ)配合物的合成与表征
摘要:
采用水相法和两相法用二氯二甲茂钛与相应的水杨酸反应合成了6个配合物:二甲基环戊二烯基水杨酸钛(Ⅰ),二甲基环戊二烯基二水杨酸钛(Ⅱ),二甲基环戊二烯基5-硝基水杨酸钛(Ⅲ),二甲基环戊二烯基二5-硝基水杨酸钛(Ⅳ),二甲基环戊二烯基3,5-二硝基水杨酸钛(Ⅴ),二甲基环戊二烯基硫代水杨酸钛(Ⅵ).对这些化合物进行了元素分析,测定了熔点,讨论了它们的红外光谱和核磁共振谱.
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关键词:
- 二甲茂水杨酸钛(Ⅳ)配合物
- / 水相法
- / 两相法
- / 合成
- / 甲基环戊二烯
English
Synthesis and Characterization of Dimethylcyclo-pentadienyl Salicylato- and Ring-substituted Salicylato-Titanium(Ⅳ) Complexes
Abstract:
Six title complexes have been prepared from dimethylcyclopentadienyl dichloro titanium and salicylic acid, mercaptosalicylic acid, 5-nitrosalicylic acid, 3,5-dinitrosalicylic acid via aqueous-phase and two-phase processes. The IR and 1H NMR spectra of the complexes are discussed briefly.
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